硫代卡巴肼、硫代碳酰肼及其相应的脒类的过渡金属配合物与 Cu(I)、Cu(II)、Co(II)、Ni(II)、Pd(II)和 Ag(I)的配合物-综述。

Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)-A Review.

机构信息

Chemistry Department, Faculty of Science, El-Minia University, Minia 61519, Egypt.

Institute of Organic Chemistry, Karlsruher Institut fur Technologie, 76131 Karlsruhe, Germany.

出版信息

Molecules. 2023 Feb 14;28(4):1808. doi: 10.3390/molecules28041808.

This review focuses on some interesting and recent applications of transition metals towards the complexation of thiosemicarbazides, thiocarbohydrazides, and their corresponding carbazones. We started the review with a description of the chosen five metals, including Cu[Cu(I), Cu(II], Co(II), Ni(II), Pd(II), and Ag(I) and their electronic configurations. The stability of the assigned complexes was also discussed. We shed light on different routes describing the synthesis of these ligands. We also reported on different examples of the synthesis of Cu(I), Cu(II), Co(II), Ni(II), Ag(I), and Pd(II) of thiosemicarbazide and thiocarbohydrazide complexes (until 2022). This review also deals with a summary of the fruitful use of metal complexes of thiosemicarbazones and thiocarbazones ligands in the field of catalysis. Finally, this recent review focuses on the applications of these complexes related to their biological importance.

本文综述了近年来过渡金属在与硫代氨基甲脒、硫代氨基甲酰肼及其相应的脒类化合物的络合方面的一些有趣应用。我们首先描述了所选择的五种金属，包括 Cu[Cu(I), Cu(II)]、Co(II)、Ni(II)、Pd(II)和 Ag(I)及其电子构型。还讨论了指定配合物的稳定性。我们介绍了合成这些配体的不同途径。我们还报告了不同例子的合成 Cu(I)、Cu(II)、Co(II)、Ni(II)、Ag(I)和 Pd(II)的硫代氨基甲脒和硫代氨基甲酰肼配合物（截至 2022 年）。本文还综述了硫代氨基甲脒和硫代氨基甲酰肼配体的金属配合物在催化领域的有益应用。最后，本综述重点介绍了这些配合物在与其生物重要性相关的应用。