Dichalcogenide and Metal Oxide Semiconductor-Based Composite to Support Plasmonic Catalysis.

Nanocomposites comprising plasmon active metal nanostructures and semiconductors have been used to control the charge states in the metal to support catalytic activity. In this context dichalcogenides when combined with metal oxides offer the potential to control charge states in plasmonic nanomaterials. Using a model plasmonic mediated oxidation reaction -amino thiophenol ↔ -nitrophenol, we show that through the introduction of transition metal dichalcogenide nanomaterial, reaction outcomes can be influenced, achieved through controlling the occurrence of the reaction intermediate dimercaptoazobenzene by opening new electron transfer routes in a semiconductor-plasmonic system. This study demonstrates the ability to control plasmonic reactions by carefully controlling the choice of semiconductors.