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使用 CO 作为促进剂和羧化试剂的电羧化反应。

Eletrocarboxylation Reactions Using CO Both as Promoter and Carboxylative Reagent.

机构信息

State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, P. R. China.

出版信息

Chemistry. 2023 Jun 7;29(32):e202204073. doi: 10.1002/chem.202204073. Epub 2023 Apr 27.

Abstract

Electrocarboxylation reaction, which employs organic electrosynthesis to achieve the utilization of CO as a carboxylative reagent, provides a powerful and efficient tool for the preparation of organic carboxylic acid. In some electrocarboxylation reactions, CO also acts as a promoter to facilitate the desired reaction. This concept mainly highlights recent CO -promoted electrocarboxylation reactions via CO intermediate or transiently protective carboxylation of active intermediate with CO .

摘要

电羧化反应利用有机电化学合成实现了 CO 作为羧化试剂的利用,为有机羧酸的制备提供了一种强大而有效的工具。在一些电羧化反应中,CO 也作为促进剂促进所需反应的进行。这一概念主要强调了最近通过 CO 中间物或 CO 对活性中间物的瞬时保护羧化促进的 CO 促进的电羧化反应。

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