State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, P. R. China.
Chemistry. 2023 Jun 7;29(32):e202204073. doi: 10.1002/chem.202204073. Epub 2023 Apr 27.
Electrocarboxylation reaction, which employs organic electrosynthesis to achieve the utilization of CO as a carboxylative reagent, provides a powerful and efficient tool for the preparation of organic carboxylic acid. In some electrocarboxylation reactions, CO also acts as a promoter to facilitate the desired reaction. This concept mainly highlights recent CO -promoted electrocarboxylation reactions via CO intermediate or transiently protective carboxylation of active intermediate with CO .
电羧化反应利用有机电化学合成实现了 CO 作为羧化试剂的利用，为有机羧酸的制备提供了一种强大而有效的工具。在一些电羧化反应中，CO 也作为促进剂促进所需反应的进行。这一概念主要强调了最近通过 CO 中间物或 CO 对活性中间物的瞬时保护羧化促进的 CO 促进的电羧化反应。
