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[沥青和柏油路面施工过程中芳香多环烃的出现情况]

[Appearance of aromatic polycyclic hydrocarbons during construction of asphalt and tar road surfaces].

作者信息

Braszczyńska Z, Osińska R, Linscheid D, Smolik E

机构信息

Instytutu Medycyny Pracy w Przemyśle Weglowym i Hutniczym w Sosnowcu.

出版信息

Med Pr. 1987;38(4):259-67.

PMID:3695932
Abstract

The dust was sampled using personal samplers and stationary aspirators. PAHs were determined by thin layer chromatography and spectrophotometry in the UV and Vis range. In the samples the concentrations of coal tar pitch volatiles (benzene extract) and phenanthrene, fluoranthene, pyrene, chrysene, tetraphene, benzo(a)pyrene, benzo(e)pyrene, perylene, 1,12 benzoperylene, indeno(1,2,3-cd) pyrene were determined. The qualitative analysis identified all these hydrocarbons but only fluoranthene, pyrene, chrysene, tetraphene and benzo(a)pyrene could be quantitatively determined. The benzene extract concentration exceeds the value of 0.2 mg/m3 in 50% of samples. Much higher results were obtained for tar-concrete (1.45-2.85 mg/m3) than for asphalt-concrete (0.14-0.71 mg/m3). Also the drivers are exposed to excess benzene extract concentrations (0.055-0.669 mg/m3). Laboratory workers were found to be exposed to high concentrations of PAH and several solvents.

摘要

使用个人采样器和固定吸气器对灰尘进行采样。通过薄层色谱法以及紫外和可见光范围内的分光光度法测定多环芳烃。在样品中测定了煤焦油沥青挥发物(苯提取物)以及菲、荧蒽、芘、 Chrysene、 Tetraphene、苯并(a)芘、苯并(e)芘、苝、 1,12-苯并苝、茚并(1,2,3-cd)芘的浓度。定性分析鉴定出了所有这些碳氢化合物,但只有荧蒽、芘、 Chrysene、 Tetraphene和苯并(a)芘能够进行定量测定。50%的样品中苯提取物浓度超过了0.2毫克/立方米的值。焦油混凝土(1.45 - 2.85毫克/立方米)的结果比沥青混凝土(0.14 - 0.71毫克/立方米)高得多。司机也暴露于过量的苯提取物浓度(0.055 - 0.669毫克/立方米)中。发现实验室工作人员暴露于高浓度的多环芳烃和几种溶剂中。

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