钌（II）催化的氧化锍叶立德与胺的偶联反应：α-酮酰胺和吲哚并[2,1 -]异喹啉的高效合成
Ru(II)-catalyzed oxidative coupling of sulfoxonium ylides with amines: efficient synthesis of α-ketoamides and indolo[2,1-]isoquinolines.
作者信息
Changmai Sumi, Gogoi Tribeni, Phukon Jyotshna, Das Bipul, Gogoi Sanjib
机构信息
Applied Organic Chemistry, Chemical Sciences & Technology Division, CSIR-North East Institute of Science and Technology, Jorhat 785006, India.
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India.
出版信息
Org Biomol Chem. 2023 Apr 12;21(15):3235-3244. doi: 10.1039/d3ob00187c.
PMID:36994697
Abstract
The first use of sulfoxonium ylides for the synthesis of α-ketoamides is described a Ru(II)-catalyzed amidation reaction with amines. The same Ru(II)-catalyzed reaction of sulfoxonium ylides with 2-phenylindoles provided indolo[2,1-]isoquinolines instead of α-ketoamides.
摘要
描述了首次使用锍叶立德通过与胺的Ru（II）催化酰胺化反应来合成α-酮酰胺。锍叶立德与2-苯基吲哚的相同Ru（II）催化反应得到的是吲哚并[2,1-]异喹啉而不是α-酮酰胺。
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