Ersoy Hüseyin, Çavuş Murat
Department of Civil Engineering, Tokat Gaziosmanpasa University, 60150, Tokat, Türkiye.
Environ Sci Pollut Res Int. 2023 Apr;30(20):58813-58826. doi: 10.1007/s11356-023-26663-5. Epub 2023 Mar 30.
This study investigates the effect of curing temperature and foam/slag ratio on NaSiO- and NaOH-activated slag-based geopolymer foam composites (GFC) having thermal insulation properties. In this regard, samples used in the study were produced by adding foam at three different ratios (12.5, 15, and 17.5% by weight of slag) to the slag-based GFC having solutions with two different activator concentrations (7 M NaOH and 3 M NaSiO). Then, these samples were exposed to three different curing temperatures (40, 60, and 22 °C). The compressive strength, dry density, unit weight, water absorption, capillarity, apparent porosity, ultrasonic pulse velocity, and thermal conductivity tests were performed on the GFC samples for 1, 3, 7, and 28 days. Scanning electron microscopy (SEM) analyses were also conducted to characterize the pore structure and crack development of the GFCs. In addition, XRD analyses were performed on selected series to determine the formed reaction products of GFCs. As a result, it was observed that high curing temperature both improved mechanical strength and physical properties in GFC samples. The highest mechanical strength was obtained in the GFC with a 12.5% foam ratio and curing at 60 °C, while the lowest thermal conductivity coefficient was achieved in GFC with a 17.5% foam ratio and cured at 60 °C. In general, with the increase of foam ratio in slag-based GFC samples, unit weight, compressive strength, and ultrasonic pulse velocity results decreased, while capillarity, water absorption, and apparent porosity results increased. According to the results, it was seen that slag-based GFCs could be used in the construction of load-bearing and non-load-bearing walls.
本研究调查了养护温度和泡沫/矿渣比,对具有保温性能的硅酸钠和氢氧化钠激发矿渣基地质聚合物泡沫复合材料(GFC)的影响。在这方面,本研究中使用的样品是通过向具有两种不同激发剂浓度(7M氢氧化钠和3M硅酸钠)溶液的矿渣基GFC中,添加三种不同比例(矿渣重量的12.5%、15%和17.5%)的泡沫来制备的。然后,将这些样品置于三种不同的养护温度(40℃、60℃和22℃)下。对GFC样品进行了1天、3天、7天和28天的抗压强度、干密度、单位重量、吸水率、毛细作用、表观孔隙率、超声波脉冲速度和热导率测试。还进行了扫描电子显微镜(SEM)分析,以表征GFC的孔隙结构和裂纹发展。此外,对选定系列进行了XRD分析,以确定GFC形成的反应产物。结果表明,高温养护既能提高GFC样品的机械强度,又能改善其物理性能。在泡沫比例为12.5%且在60℃养护的GFC中获得了最高的机械强度,而在泡沫比例为17.5%且在60℃养护的GFC中获得了最低的热导率系数。一般来说,随着矿渣基GFC样品中泡沫比例的增加,单位重量、抗压强度和超声波脉冲速度结果降低,而毛细作用、吸水率和表观孔隙率结果增加。根据结果可知,矿渣基GFC可用于承重墙和非承重墙的建造。