State Key Laboratory of Biobased Material and Green Papermaking, Key Laboratory of Pulp & Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China.
State Key Laboratory of Biobased Material and Green Papermaking, Key Laboratory of Pulp & Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China; Department of Chemical Engineering, Lakehead University, 955 Oliver Road, Thunder Bay, ON P7B 5E1, Canada.
Int J Biol Macromol. 2023 Jun 15;240:124368. doi: 10.1016/j.ijbiomac.2023.124368. Epub 2023 Apr 5.
Utilization of kraft lignin to produce bio-based adsorptive material for effective dye adsorption from industrial wastewater is essential to fulfilling the significant environmental protection needs. Lignin is the most abundant byproduct material with a chemical structure containing various functional groups. However, the complicated chemical structure makes it somewhat hydrophobic and incompatible, which limits its direct application as an adsorption material. Chemical modification is a common way to enhance lignin properties. In this work, the kraft lignin was modified through direct amination using Mannich reaction and oxidization followed by amination as new route of lignin modification. The prepared lignins, including aminated lignin (AL), oxidized lignin (OL), and aminated-oxidized lignin (AOL), as well as unmodified kraft lignin, were analyzed by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), elemental analysis and H-nuclear magnetic resonance measurements (HNMR). The adsorption behaviors of modified lignins for the malachite green in aqueous solution were investigated well and discussed, as well as the adsorption kinetics and thermodynamic equations. Compared with other aminated lignin (AL), the AOL displayed a high adsorption capacity of 99.1 % dye removal, due to its more effective functional groups. The change in structure and functional groups on the lignin molecules during oxidation and amination had no effect on its adsorption mechanisms. The adsorption process of malachite green on different kinds of lignin belongs to endothermic chemical adsorption, which mainly consists of monolayer adsorption. The modification of lignin through oxidation followed by amination process, afforded kraft lignin a broad potential application in the field of wastewater treatment.
利用木质素生产生物基吸附材料,从工业废水中有效吸附染料,这对于满足重要的环境保护需求至关重要。木质素是最丰富的副产物材料,其化学结构含有各种官能团。然而,复杂的化学结构使其具有一定的疏水性和不兼容性,限制了其直接作为吸附材料的应用。化学修饰是增强木质素性能的常用方法。在这项工作中,采用曼尼希反应的直接胺化和氧化后胺化对木质素进行修饰,开辟了木质素修饰的新途径。通过傅里叶变换红外光谱(FT-IR)、热重分析(TGA)、扫描电子显微镜(SEM)、X 射线光电子能谱(XPS)、元素分析和 H 核磁共振测量(HNMR)对木质素进行了分析。研究了改性木质素对水溶液中孔雀石绿的吸附行为,并对吸附动力学和热力学方程进行了讨论。与其他胺化木质素(AL)相比,AOL 显示出 99.1%的高染料去除率,这是由于其具有更多有效的官能团。氧化和胺化过程中木质素分子结构和官能团的变化对其吸附机制没有影响。不同种类的木质素对孔雀石绿的吸附过程属于吸热化学吸附,主要由单层吸附组成。通过氧化后胺化的木质素修饰过程,赋予了木质素在废水处理领域广泛的潜在应用。