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基于局域表面等离子体共振的金纳米粒子涂覆无覆层单模光纤传感器。

A gold nanoparticles coated unclad single mode fiber-optic sensor based on localized surface plasmon resonance.

机构信息

Laser and Optoelectronic Engineering Department, University of Technology-Iraq, Baghdad, Iraq.

Applied science department, University of Technology-Iraq, Baghdad, Iraq.

出版信息

Sci Rep. 2023 Apr 7;13(1):5680. doi: 10.1038/s41598-023-32852-6.

Abstract

In the last few decays, the fiber-optic was employed in the field of sensing because of its benefits in contrast to other types of sensors such as small size, easy to fabricate, high response, and flexibility. In this study, unclad single mode fiber-optic sensor is proposed to operate at 650 nm wavelength. COMSOL Multiphysics 5.1 finite element method (FEM) is used to design the sensor and tested it theoretically. The middle portion of the fiber cladding is removed and replaced by gold nanoparticles (Au NPs) of 50 nm thickness. Analytic layer of 3 μm thickness was immersed in different liquids in range of refractive index (RI) from 1.000281 to 1.39. These liquids are NaCl Deionized (DI) water solution, sucrose-Deionized (DI) water solution, and glycerol solution Deionized (DI) water. It was found that the highest obtained sensitivity and resolution are for glycerol-DI water solution with value of 3157.98 (nm/RIU) and 3.16 × 10 (RIU), respectively. Furthermore, it is easy to fabricate and of low cost. In experiments, pulsed laser ablation (PLA) was used to prepare Au NPs. X-ray diffraction (XRD) shown that the peak of the intensity grew as the ablated energy increased as well as the structure crystallization. Transmission electron microscopy (TEM) revealed an average diameter of 30 nm at the three ablated energies, while X-ray spectroscopy (EDX) spectrum has indicated the presence of Au NPs in the prepared solution. The photoluminescence (PL) and ultraviolet-visible UV-Vis transmission were used to study the optical properties of the prepared Au NPs. An optical spectrum analyzer was used to obtain the sensor's output results. It has shown that best intensity was obtained for sucrose which confined with theoretical results.

摘要

在过去的几十年中,由于光纤在尺寸小、易于制造、高响应和灵活性等方面的优势,在传感领域得到了广泛应用。本研究提出了一种工作在 650nm 波长的无涂层单模光纤传感器。使用 COMSOL Multiphysics 5.1 有限元法(FEM)设计传感器并进行理论测试。光纤包层的中间部分被去除,并被 50nm 厚的金纳米粒子(Au NPs)取代。厚度为 3μm 的分析层浸入不同折射率(RI)范围从 1.000281 到 1.39 的液体中。这些液体是 NaCl 去离子(DI)水、蔗糖-DI 水和甘油-DI 水。结果发现,甘油-DI 水的灵敏度和分辨率最高,分别为 3157.98(nm/RIU)和 3.16×10(RIU)。此外,该传感器易于制造且成本低。在实验中,采用脉冲激光烧蚀(PLA)制备 Au NPs。X 射线衍射(XRD)表明,随着烧蚀能量的增加,强度峰值增加,结构结晶度也增加。透射电子显微镜(TEM)显示在三个烧蚀能量下的平均直径为 30nm,而 X 射线能谱(EDX)谱表明在制备的溶液中存在 Au NPs。光致发光(PL)和紫外可见(UV-Vis)透射用于研究制备的 Au NPs 的光学性质。使用光谱分析仪获得传感器的输出结果。结果表明,蔗糖的强度最好,这与理论结果一致。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c924/10082208/4ee946668f31/41598_2023_32852_Fig1_HTML.jpg

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