Xu Lingfeng, Peng Hui, Ma Gengxiang, Huang Yanrong
Key Laboratory of Biodiversity and Ecological Engineering of Jiangxi Province, Jinggangshan University, Ji'an, 343009 Jiangxi China.
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence From Molecular Aggregates, College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640 China.
J Food Sci Technol. 2023 May;60(5):1570-1579. doi: 10.1007/s13197-023-05699-y. Epub 2023 Feb 27.
A noninvasive and effective viscosity inspection method is expected to ease the burden of continued increased health problems caused by liquid food safety. In this study, we proposed the viscosity of the liquid food micro-environment as a marker and further developed a versatile optical sensor, , for monitoring liquid food micro-environmental viscosity alterations. This sensor was strategically constructed by the triphenylamine-thiophene derivate and michaelitic acid, rotatable conjugate structure was utilized as the recognition site. The molecular sensor was synthesized in a one-step facile way, and displayed a longer emission wavelength (592 nm), low detection limit (1.419 cP), and larger Stokes shift (193.7 nm in glycerol and 177.8 nm in water) with narrower energy band, endowing the sensor with the capacity of achieving high signal-to-noise ratio imaging. Meanwhile, exhibits high adaptability, selectivity, sensitivity, and good photo-stability in various liquid foods, bright fluorescent signal (37.5-fold) of is specifically activated in the high viscosity media. Thickening efficiencies can be identified as well. More importantly, the viscosity fluctuations during the metamorphic stages of liquid foods are also screened through in situ monitoring. We expected that this unique strategy will reinvigorate the continued perfection of liquid food safety investigation systems.
The online version contains supplementary material available at 10.1007/s13197-023-05699-y.
一种非侵入性且有效的粘度检测方法有望减轻因液体食品安全导致的持续增加的健康问题负担。在本研究中,我们提出将液体食品微环境的粘度作为一个指标,并进一步开发了一种多功能光学传感器,用于监测液体食品微环境粘度的变化。该传感器由三苯胺 - 噻吩衍生物和迈克尔酸精心构建而成,利用可旋转共轭结构作为识别位点。分子传感器以一步简便的方式合成,发射波长较长(592 nm),检测限低(1.419 cP),斯托克斯位移较大(在甘油中为193.7 nm,在水中为177.8 nm)且能带较窄,赋予传感器实现高信噪比成像的能力。同时,该传感器在各种液体食品中表现出高适应性、选择性、灵敏度和良好的光稳定性,在高粘度介质中特异性激活的荧光信号增强(37.5倍)。还可以识别增稠效率。更重要的是,通过原位监测还能筛选出液体食品变质阶段的粘度波动。我们期望这种独特的策略将重振液体食品安全调查系统的持续完善。
在线版本包含可在10.1007/s13197 - 023 - 05699 - y获取的补充材料。