Laser Emission Spectroscopy of Graphene Oxide Deposited on 316 Steel and Ti6Al4V Titanium Alloy Suitable for Orthopedics.

This paper presents the results of an analysis of carbon (in the form of graphene oxide) deposited on the surface of threads made from stainless steel 316 and titanium alloy Ti6Al4V used in orthopedics using Laser Induced Breakdown Spectroscopy (LIBS). The aim of the article is to indicate the possibility of using the LIBS spectra for the study of thin layers, including graphene derivatives and other elements. Stratigraphic measurements allowed the detection of differences in the spectra peaks of individual elements, not only in the surface layer itself and in the native material, but also in the intermediate layer connecting the two layers. Due to the clear difference in the outline of the spectrum of graphene oxide and the spectrum of the native material of the samples analyzed, a clear incorporation of carbon atoms into the surface layer was observed. A factor analysis was performed, which confirmed the incorporation of graphene oxide into the surface layer of the native material of the elements examined.