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可穿戴可拉伸的SEBS/CB聚合物导电丝作为压阻式应变传感器

Wearable and Stretchable SEBS/CB Polymer Conductive Strand as a Piezoresistive Strain Sensor.

作者信息

Jamatia Thaiskang, Matyas Jiri, Olejnik Robert, Danova Romana, Maloch Jaroslav, Skoda David, Slobodian Petr, Kuritka Ivo

机构信息

Centre of Polymer Systems, Tomas Bata University in Zlín, Tr. Tomase Bati 5678, 760 01 Zlin, Czech Republic.

Department of Physics and Materials Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavrečkova 5669, 760 01 Zlin, Czech Republic.

出版信息

Polymers (Basel). 2023 Mar 24;15(7):1618. doi: 10.3390/polym15071618.

DOI:10.3390/polym15071618
PMID:37050233
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10096618/
Abstract

A wearable and stretchable strain sensor with a gauge factor above 23 was prepared using a simple and effective technique. Conducting nanocomposite strands were prepared from styrene-b-(ethylene-co-butylene)-b-styrene triblock copolymer (SEBS) and carbon black (CB) through a solvent-processing method that uses a syringe pump. This novel nanocomposite preparation technique is a straightforward and cost-effective process and is reported in the literature for the first time. The work included two stages: the flexible nanocomposite preparation stage and the piezoresistive sensor stage. Depending on its molecular structure, the thermoelastic polymer SEBS is highly resilient to stress and strain. The main aim of this work is to fabricate a highly flexible and piezoresistive nanocomposite fibre/strand. Among the prepared composites, a composite corresponding to a composition just above the percolation threshold was selected to prepare the strain sensor, which exhibited good flexibility and conductivity and a large piezoresistive effect that was linearly dependent on the applied strain. The prepared nanocomposite sensor was stitched onto a sports T-shirt. Commercially available knee and elbow sleeves were also purchased, and the nanocomposite SEBS/CB strands were sewn separately on the two sleeves. The results showed a high sensitivity of the sensing element in the case of breathing activity (normal breathing, a 35% change, and deep breathing at 135%, respectively). In the case of knee and elbow movements, simultaneous measurements were performed and found that the sensor was able to detect movement cycles during walking.

摘要

采用一种简单有效的技术制备了一种应变系数高于23的可穿戴、可拉伸应变传感器。通过使用注射泵的溶剂处理方法,由苯乙烯 - b -(乙烯 - 共 - 丁烯) - b - 苯乙烯三嵌段共聚物(SEBS)和炭黑(CB)制备导电纳米复合线。这种新型纳米复合材料制备技术是一种直接且具有成本效益的工艺,首次在文献中报道。这项工作包括两个阶段:柔性纳米复合材料制备阶段和压阻传感器阶段。根据其分子结构,热弹性聚合物SEBS对应力和应变具有高度弹性。这项工作的主要目的是制造一种高度柔性且具有压阻性的纳米复合纤维/线。在制备的复合材料中,选择一种对应于略高于渗流阈值组成的复合材料来制备应变传感器,该传感器表现出良好的柔韧性和导电性以及与施加应变呈线性相关的大压阻效应。将制备的纳米复合传感器缝在一件运动T恤上。还购买了市售的膝盖和肘部护具,并将纳米复合SEBS/CB线分别缝在两个护具上。结果表明,在呼吸活动(正常呼吸时变化35%,深呼吸时变化135%)的情况下,传感元件具有高灵敏度。在膝盖和肘部运动的情况下,进行了同步测量,发现该传感器能够检测行走过程中的运动周期。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/456372c2afa0/polymers-15-01618-g014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/b2c70ccee6a4/polymers-15-01618-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/5b942220aac9/polymers-15-01618-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/e78d507b76e2/polymers-15-01618-g003.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/e16a74d62d17/polymers-15-01618-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/8321f423237b/polymers-15-01618-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/54be2da32d99/polymers-15-01618-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/4b66106c242e/polymers-15-01618-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/3e755f59c758/polymers-15-01618-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/824f/10096618/456372c2afa0/polymers-15-01618-g014.jpg

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