• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

阴离子氨基铁（II）配合物的合成与催化作用

Synthesis and Catalysis of Anionic Amido Iron(II) Complexes.

作者信息

Chakraborty Uttam, Fedulin Andrey, Jacobi von Wangelin Axel

机构信息

Department of Chemistry University of Hamburg Martin Luther King Pl 6 20146 Hamburg Germany.

出版信息

ChemCatChem. 2022 Dec 20;14(24):e202201105. doi: 10.1002/cctc.202201105. Epub 2022 Nov 24.

DOI:10.1002/cctc.202201105
PMID:37064762
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10099668/
Abstract

Low-coordinate, open-shell 3d metal complexes have attracted great attention due to their critical role in several catalytic transformations but have been notoriously difficult to prepare and study due to their high lability. Here, we report the synthesis of a heteroleptic tri-coordinate amidoferrate that displays high catalytic activity in the regioselective hydrosilylation of alkenes.

摘要

低配位、开壳层的3d金属配合物因其在多种催化转化中发挥的关键作用而备受关注，但因其高活性而极难制备和研究。在此，我们报道了一种杂配三配位酰胺基铁酸盐的合成，该化合物在烯烃的区域选择性硅氢化反应中表现出高催化活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/828e7793cad8/CCTC-14-0-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/c1d78d63ea58/CCTC-14-0-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/ae3edd673d31/CCTC-14-0-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/aa00d7649b0a/CCTC-14-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/1631e5d95e03/CCTC-14-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/2a755e7a9600/CCTC-14-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/828e7793cad8/CCTC-14-0-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/c1d78d63ea58/CCTC-14-0-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/ae3edd673d31/CCTC-14-0-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/aa00d7649b0a/CCTC-14-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/1631e5d95e03/CCTC-14-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/2a755e7a9600/CCTC-14-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1da4/10099668/828e7793cad8/CCTC-14-0-g001.jpg

相似文献

1
Synthesis and Catalysis of Anionic Amido Iron(II) Complexes.阴离子氨基铁（II）配合物的合成与催化作用
ChemCatChem. 2022 Dec 20;14(24):e202201105. doi: 10.1002/cctc.202201105. Epub 2022 Nov 24.
2
Notable Catalytic Activity of Transition Metal Thiolate Complexes against Hydrosilylation and Hydroboration of Carbon-Heteroatom Bonds.过渡金属硫醇配合物对碳杂原子键的硅氢化和硼氢化反应的显著催化活性。
Chem Asian J. 2023 Feb 1;18(3):e202201181. doi: 10.1002/asia.202201181. Epub 2023 Jan 2.
3
Synthesis of divalent ytterbium terphenylamide and catalytic application for regioselective hydrosilylation of alkenes.二价三联苯酰胺镱的合成及其对烯烃区域选择性硅氢化反应的催化应用
Dalton Trans. 2017 Aug 22;46(33):10957-10962. doi: 10.1039/c7dt01837a.
4
An Iron(II) Ylide Complex as a Masked Open-Shell Iron Alkylidene Species in Its Alkylidene-Transfer Reactions with Alkenes.铁(II)叶立德配合物作为掩蔽的开壳态铁亚烷基物种在其与烯烃的亚烷基转移反应中的应用。
J Am Chem Soc. 2017 Mar 15;139(10):3876-3888. doi: 10.1021/jacs.7b00484. Epub 2017 Mar 1.
5
Lanthanide amido complexes incorporating amino-coordinate-lithium bridged bis(indolyl) ligands: synthesis, characterization, and catalysis for hydrophosphonylation of aldehydes and aldimines.镧系酰胺配合物，包含氨基配位的锂桥联双（吲哚基）配体：合成、表征及对醛和亚胺的氢膦酰化反应的催化作用。
Inorg Chem. 2012 Jul 2;51(13):7134-43. doi: 10.1021/ic300137r. Epub 2012 Jun 19.
6
Phenanthroline-imine ligands for iron-catalyzed alkene hydrosilylation.用于铁催化烯烃硅氢化反应的菲咯啉-亚胺配体。
Chem Sci. 2022 Feb 10;13(9):2721-2728. doi: 10.1039/d1sc06727c. eCollection 2022 Mar 2.
7
Enabling Nucleophilic Reactivity in High-Spin Fe(II) Imido Complexes: From Elementary Steps to Cooperative Catalysis.在高自旋Fe(II)亚胺配合物中实现亲核反应活性：从基本步骤到协同催化
Acc Chem Res. 2023 Dec 5;56(23):3392-3403. doi: 10.1021/acs.accounts.3c00511. Epub 2023 Nov 13.
8
Cooperative Catalysis at Metal-Sulfur Bonds.金属-硫键的协同催化作用。
Acc Chem Res. 2017 May 16;50(5):1258-1269. doi: 10.1021/acs.accounts.7b00089. Epub 2017 Apr 13.
9
Synthesis and characterization of anionic rare-earth metal amides stabilized by phenoxy-amido ligands and their catalytic behavior for the polymerization of lactide.合成与表征酚氧基酰胺配体稳定的阴离子稀土金属酰胺及其在丙交酯聚合中的催化性能。
Dalton Trans. 2010 Oct 28;39(40):9530-7. doi: 10.1039/c0dt00025f. Epub 2010 Sep 3.
10
Copper, silver, and gold complexes in hydrosilylation reactions.硅氢化反应中的铜、银和金配合物。
Acc Chem Res. 2008 Feb;41(2):349-58. doi: 10.1021/ar7001655.

引用本文的文献

1
Cobalt-catalyzed double hydroboration of pyridines.钴催化吡啶的双硼氢化反应
Chem Sci. 2024 Mar 8;15(14):5201-5210. doi: 10.1039/d3sc05418g. eCollection 2024 Apr 3.

本文引用的文献

1
Intricate Road to Linear Anionic Nickel(I) Hexamethyldisilazanide [Ni(N(SiMe))].通往线性阴离子六甲基二硅氮烷镍（I）[Ni(N(SiMe)₃)]的复杂之路。
Inorg Chem. 2022 May 23;61(20):7794-7803. doi: 10.1021/acs.inorgchem.2c00214. Epub 2022 May 6.
2
Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand.使用硅基（双）酰胺配体稳定的钾 TMP-锌试剂实现对氟代芳烃的金属化反应。
Chem Commun (Camb). 2022 Apr 26;58(34):5292-5295. doi: 10.1039/d2cc00979j.
3
Paramagnetic Li NMR Shifts and Magnetic Properties of Divalent Transition Metal Silylamide Ate Complexes [LiM{N(SiMe)}] (M = Mn, Fe, Co).
二价过渡金属硅烷基酰胺酸根配合物[LiM{N(SiMe)}]（M = Mn、Fe、Co）的顺磁锂核磁共振位移和磁性
Inorg Chem. 2022 Jan 10;61(1):554-567. doi: 10.1021/acs.inorgchem.1c03237. Epub 2021 Dec 21.
4
Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands.含庞大的2,6-二异丙基-N-（三甲基硅基）苯胺配体的高铁酸钠的侧向金属化和再分布反应。
Chemistry. 2021 Nov 2;27(61):15180-15186. doi: 10.1002/chem.202102328. Epub 2021 Sep 12.
5
Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling.二锂酰胺作为模块化双负离子配体平台在铁催化交叉偶联反应中的应用。
Org Lett. 2021 Aug 6;23(15):5958-5963. doi: 10.1021/acs.orglett.1c02053. Epub 2021 Jul 26.
6
Facilitating the Ferration of Aromatic Substrates through Intramolecular Sodium Mediation.通过分子内钠介导促进芳基底物的铁化。
Angew Chem Int Ed Engl. 2021 Jul 5;60(28):15296-15301. doi: 10.1002/anie.202104275. Epub 2021 Jun 17.
7
Organic synthesis with the most abundant transition metal-iron: from rust to multitasking catalysts.利用最丰富的过渡金属-铁进行有机合成：从铁锈到多功能催化剂。
Chem Soc Rev. 2021 Jan 7;50(1):243-472. doi: 10.1039/d0cs00688b. Epub 2021 Jan 5.
8
Lithium-mediated Ferration of Fluoroarenes.锂介导的氟代芳烃铁化反应
Chimia (Aarau). 2020 Nov 25;74(11):866-870. doi: 10.2533/chimia.2020.866.
9
Catalytic Selective Dihydrosilylation of Internal Alkynes Enabled by Rare-Earth Ate Complex.稀土酸根络合物实现的内炔催化选择性二氢硅基化反应
Angew Chem Int Ed Engl. 2020 Feb 3;59(6):2365-2369. doi: 10.1002/anie.201913773. Epub 2020 Jan 3.
10
Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.贱金属（铁、钴和镍）在硼氢化和硅氢化反应中的出现和应用。
Molecules. 2019 Sep 3;24(17):3194. doi: 10.3390/molecules24173194.