Aguirre Miren, Ballard Nicholas, Gonzalez Edurne, Hamzehlou Shaghayegh, Sardon Haritz, Calderon Marcelo, Paulis Maria, Tomovska Radmila, Dupin Damien, Bean Ren H, Long Timothy E, Leiza Jose R, Asua José M
POLYMAT, Kimika Fakultatea, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, 20018 Donostia-San Sebastian, Spain.
IKERBASQUE, Basque Foundation for Science, Plaza Euskadi 5, 48009 Bilbao, Spain.
Macromolecules. 2023 Mar 23;56(7):2579-2607. doi: 10.1021/acs.macromol.3c00108. eCollection 2023 Apr 11.
Polymer colloids are complex materials that have the potential to be used in a vast array of applications. One of the main reasons for their continued growth in commercial use is the water-based emulsion polymerization process through which they are generally synthesized. This technique is not only highly efficient from an industrial point of view but also extremely versatile and permits the large-scale production of colloidal particles with controllable properties. In this perspective, we seek to highlight the central challenges in the synthesis and use of polymer colloids, with respect to both existing and emerging applications. We first address the challenges in the current production and application of polymer colloids, with a particular focus on the transition toward sustainable feedstocks and reduced environmental impact in their primary commercial applications. Later, we highlight the features that allow novel polymer colloids to be designed and applied in emerging application areas. Finally, we present recent approaches that have used the unique colloidal nature in unconventional processing techniques.
聚合物胶体是一种复杂材料,有潜力应用于大量领域。其商业用途持续增长的主要原因之一是通常用于合成它们的水基乳液聚合工艺。从工业角度来看,该技术不仅高效,而且极为通用,能够大规模生产具有可控性质的胶体颗粒。从这个角度出发,我们试图强调聚合物胶体在合成和使用方面面临的核心挑战,涵盖现有及新兴应用。我们首先探讨聚合物胶体当前生产和应用中的挑战,特别关注向可持续原料的转变以及在其主要商业应用中降低环境影响。随后,我们突出使新型聚合物胶体得以设计并应用于新兴应用领域的特性。最后,我们介绍在非常规加工技术中利用独特胶体性质的最新方法。