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动态光散射及其在控制胶体系统中纳米颗粒聚集方面的应用:综述

Dynamic Light Scattering and Its Application to Control Nanoparticle Aggregation in Colloidal Systems: A Review.

作者信息

Rodriguez-Loya Jesus, Lerma Maricarmen, Gardea-Torresdey Jorge L

机构信息

Environmental Science and Engineering Ph. D. Program, University of Texas at El Paso, El Paso, TX 79968, USA.

Department of Chemistry and Biochemistry, University of Texas at El Paso, El Paso, TX 79968, USA.

出版信息

Micromachines (Basel). 2023 Dec 22;15(1):24. doi: 10.3390/mi15010024.

Abstract

Colloidal systems and their control play an essential role in daily human activities, but several drawbacks lead to an avoidance of their extensive application in some more productive areas. Some roadblocks are a lack of knowledge regarding how to influence and address colloidal forces, as well as a lack of practical devices to understand these systems. This review focuses on applying dynamic light scattering (DLS) as a powerful tool for monitoring and characterizing nanoparticle aggregation dynamics. We started by outlining the core ideas behind DLS and how it may be used to examine colloidal particle size distribution and aggregation dynamics; then, in the last section, we included the options to control aggregation in the chemically processed toner. In addition, we pinpointed knowledge gaps and difficulties that obstruct the use of DLS in real-world situations. Although widely used, DLS has limits when dealing with complicated systems, including combinations of nanoparticles, high concentrations, and non-spherical particles. We discussed these issues and offered possible solutions and the incorporation of supplementary characterization approaches. Finally, we emphasized how critical it is to close the gap between fundamental studies of nanoparticle aggregation and their translation into real-world applications, recognizing challenges in colloidal science.

摘要

胶体系统及其控制在人类日常活动中起着至关重要的作用,但一些缺点导致它们在一些更具生产力的领域无法得到广泛应用。一些障碍包括缺乏关于如何影响和处理胶体力的知识,以及缺乏用于理解这些系统的实用设备。本综述重点介绍将动态光散射(DLS)作为监测和表征纳米颗粒聚集动力学的强大工具。我们首先概述了DLS背后的核心思想以及它如何用于研究胶体颗粒尺寸分布和聚集动力学;然后,在最后一部分,我们介绍了控制化学处理调色剂中聚集的方法。此外,我们指出了阻碍DLS在实际应用中的知识差距和困难。尽管DLS被广泛使用,但在处理复杂系统时存在局限性,包括纳米颗粒的组合、高浓度和非球形颗粒。我们讨论了这些问题,并提供了可能的解决方案以及纳入补充表征方法。最后,我们强调了弥合纳米颗粒聚集基础研究与实际应用之间差距的重要性,认识到胶体科学中的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4997/10819909/a2deece60af0/micromachines-15-00024-g001.jpg

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