Rojas Gómez Alejandro, Acosta Laura K, Ferré-Borrull Josep, Santos Abel, Marsal Lluis F
Department of Electronic, Electric, and Automatics Engineering, Rovira i Virgili University, Tarragona 43007, Spain.
School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, South Australia 5005, Australia.
ACS Appl Nano Mater. 2023 Mar 22;6(7):5274-5283. doi: 10.1021/acsanm.2c05356. eCollection 2023 Apr 14.
Gold-coated gradient-index filters based on nanoporous anodic alumina (Au-coated NAA-GIFs) were used as model platforms to elucidate how Tamm plasmons can be tailored by engineering the geometric features of the plasmonic and photonic components of these hybrid structures. NAA-GIFs with well-resolved, intense photonic stopbands at two positions of the visible spectrum were fabricated through sinusoidal pulse anodization. These model photonic crystals were used to assess how the quality of Tamm plasmon resonances can be enhanced by tuning the features of the dielectric mirror and the thickness of the porous gold coating layer. It is found that the highest value of the quality factor of Tamm resonance ( = 237) is obtained for 11 nm of gold on a dielectric mirror with low porosity corresponding to the resonant spectral position of λ of ∼698 nm. Our analysis indicates that Tamm resonances in as-produced Au-coated NAA-GIFs are weak due to the constrained range of wavelengths (narrow bands) at which these photonic crystal structures reflect light. However, after broadening of their photonic stopband upon pore widening, Tamm resonances become better resolved, with higher intensity. It is also observed that the quality of light confinement worsens progressively with the thickness of the porous gold coating layer after a critical value. In contrast to conventional surface plasmon resonance systems, this hybrid Tamm porous system does not require complex coupling systems and provides a nanoporous structure that can be readily tailored for a range of photonic technologies such as sensing and lasing.
基于纳米多孔阳极氧化铝的镀金梯度折射率滤波器(Au 涂层 NAA - GIFs)被用作模型平台,以阐明如何通过设计这些混合结构的等离子体和光子组件的几何特征来定制塔姆等离子体激元。通过正弦脉冲阳极氧化制备了在可见光谱的两个位置具有清晰、强烈光子带隙的 NAA - GIFs。这些模型光子晶体用于评估如何通过调整介质镜的特征和多孔金涂层的厚度来提高塔姆等离子体激元共振的质量。结果发现,在对应于约 698 nm 的λ共振光谱位置的低孔隙率介质镜上,当金厚度为 11 nm 时,获得了塔姆共振品质因数的最高值(Q = 237)。我们的分析表明,由于这些光子晶体结构反射光的波长范围受限(窄带),所制备的 Au 涂层 NAA - GIFs 中的塔姆共振较弱。然而,在孔隙扩大后其光子带隙变宽,塔姆共振变得更清晰,强度更高。还观察到,在达到临界值后,光限制质量随着多孔金涂层厚度的增加而逐渐变差。与传统的表面等离子体激元共振系统相比,这种混合塔姆多孔系统不需要复杂的耦合系统,并提供了一种纳米多孔结构,可轻松针对一系列光子技术(如传感和激光)进行定制。