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多孔阳极氧化铝光子晶体中线性可变带通滤波器的实现和光学工程。

Realisation and optical engineering of linear variable bandpass filters in nanoporous anodic alumina photonic crystals.

机构信息

School of Chemical Engineering, The University of Adelaide, Engineering North Building, 5005 Adelaide, Australia.

出版信息

Nanoscale. 2017 Jun 8;9(22):7541-7550. doi: 10.1039/c7nr02115a.

Abstract

We present the first realisation of linear variable bandpass filters in nanoporous anodic alumina (NAA-LVBPFs) photonic crystal structures. NAA gradient-index filters (NAA-GIFs) are produced by sinusoidal pulse anodisation and used as photonic crystal platforms to generate NAA-LVBPFs. The anodisation period of NAA-GIFs is modified from 650 to 850 s to systematically tune the characteristic photonic stopband of these photonic crystals across the UV-visible-NIR spectrum. Then, the nanoporous structure of NAA-GIFs is gradually widened along the surface under controlled conditions by wet chemical etching using a dip coating approach aiming to create NAA-LVBPFs with finely engineered optical properties. We demonstrate that the characteristic photonic stopband and the iridescent interferometric colour displayed by these photonic crystals can be tuned with precision across the surface of NAA-LVBPFs by adjusting the fabrication and etching conditions. Here, we envisage for the first time the combination of the anodisation period and etching conditions as a cost-competitive, facile, and versatile nanofabrication approach that enables the generation of a broad range of unique LVBPFs covering the spectral regions. These photonic crystal structures open new opportunities for multiple applications, including adaptive optics, hyperspectral imaging, fluorescence diagnostics, spectroscopy, and sensing.

摘要

我们首次在纳米多孔阳极氧化铝(NAA-LVBPFs)光子晶体结构中实现了线性可变带通滤波器。通过正弦脉冲阳极氧化法制备梯度折射率滤光片(NAA-GIFs),并将其用作光子晶体平台以生成 NAA-LVBPFs。通过将 NAA-GIFs 的阳极氧化周期从 650 秒修改为 850 秒,系统地调节了这些光子晶体在紫外可见近红外光谱范围内的特征光子带隙。然后,通过使用浸涂方法在受控条件下对 NAA-GIFs 的纳米多孔结构进行湿化学蚀刻,使其沿表面逐渐变宽,旨在创建具有精细工程光学性能的 NAA-LVBPFs。我们证明,通过调整制造和蚀刻条件,可以精确地在 NAA-LVBPFs 的表面上调节这些光子晶体的特征光子带隙和彩虹干涉色。在这里,我们首次设想将阳极氧化周期和蚀刻条件相结合,作为一种具有成本竞争力、简便且通用的纳米制造方法,可以生成涵盖整个光谱区域的一系列独特的 LVBPFs。这些光子晶体结构为自适应光学、高光谱成像、荧光诊断、光谱学和传感等多种应用开辟了新的机会。

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