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镁含量对可降解Zn-0.5Mn-xMg合金微观结构、力学性能及细胞相容性的影响

Effect of Mg Contents on the Microstructure, Mechanical Properties and Cytocompatibility of Degradable Zn-0.5Mn-xMg Alloy.

作者信息

Yang Lingbo, Li Xing, Yang Lijing, Zhu Xinglong, Wang Manli, Song Zhenlun, Liu Huinan Hannah, Sun Wensheng, Dong Ruihong, Yue Jiqiang

机构信息

School of Materials Sciences and Chemical Engineering, Ningbo University, Ningbo 315000, China.

Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.

出版信息

J Funct Biomater. 2023 Mar 31;14(4):195. doi: 10.3390/jfb14040195.

Abstract

The effect of magnesium (Mg) content on the microstructure, mechanical properties, and cytocompatibility of degradable Zn-0.5Mn-xMg (x = 0.05 wt%, 0.2 wt%, 0.5 wt%) alloys was investigated. The microstructure, corrosion products, mechanical properties, and corrosion properties of the three alloys were then thoroughly characterized by scanning electron microscopy (SEM), electron back-scattered diffraction (EBSD), and other methods. According to the findings, the grain size of matrix was refined by the addition of Mg, while the size and quantity of MgZn phase was increased. The Mg content could significantly improve the ultimate tensile strength (UTS) of the alloy. Compared with the Zn-0.5Mn alloy, the UTS of Zn-0.5Mn-xMg alloy was increased significantly. Zn-0.5Mn-0.5Mg exhibited the highest UTS (369.6 MPa). The strength of the alloy was influenced by the average grain size, the solid solubility of Mg, and the quantity of MgZn phase. The increase in the quantity and size of MgZn phase was the main reason for the transition from ductile fracture to cleavage fracture. Moreover, Zn-0.5Mn-0.2Mg alloy showed the best cytocompatibility to L-929 cells.

摘要

研究了镁(Mg)含量对可降解Zn-0.5Mn-xMg(x = 0.05 wt%、0.2 wt%、0.5 wt%)合金的微观结构、力学性能和细胞相容性的影响。然后通过扫描电子显微镜(SEM)、电子背散射衍射(EBSD)等方法对这三种合金的微观结构、腐蚀产物、力学性能和腐蚀性能进行了全面表征。研究结果表明,添加Mg细化了基体的晶粒尺寸,同时增加了MgZn相的尺寸和数量。Mg含量可显著提高合金的抗拉强度(UTS)。与Zn-0.5Mn合金相比,Zn-0.5Mn-xMg合金的UTS显著提高。Zn-0.5Mn-0.5Mg表现出最高的UTS(369.6 MPa)。合金的强度受平均晶粒尺寸、Mg的固溶度以及MgZn相数量的影响。MgZn相数量和尺寸的增加是从韧性断裂转变为解理断裂的主要原因。此外,Zn-0.5Mn-0.2Mg合金对L-929细胞表现出最佳的细胞相容性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f3c/10145424/b21c800c1dcf/jfb-14-00195-g001.jpg

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