Appl Opt. 2023 Apr 20;62(12):2970-2977. doi: 10.1364/AO.477193.
A study on the classification of copper concentrates relevant to the copper refining industry is performed by means of reflectance hyperspectral images in the visible and near infrared (VIS-NIR) bands (400-1000 nm) and in the short-wave infrared (SWIR) (900-1700 nm) band. A total of 82 copper concentrate samples were press compacted into 13-mm-diameter pellets, and their mineralogical composition was characterized via quantitative evaluation of minerals and scanning electron microscopy. The most representative minerals contained in these pellets are bornite, chalcopyrite, covelline, enargite, and pyrite. Three databases (VIS-NIR, SWIR, and VIS-NIR-SWIR) containing a collection of average reflectance spectra computed from 9×9 neighborhoods in each pellet hyperspectral image are compiled to train the classification models. The classification models tested in this work are a linear discriminant classifier and two non-linear classifiers, a quadratic discriminant classifier, and a fine -nearest neighbor classifier (FKNNC). The results obtained show that the joint use of VIS-NIR and SWIR bands allows for the accurate classification of similar copper concentrates that contain only minor differences in their mineralogical composition. Specifically, among the three tested classification models, the FKNNC performs the best in terms of overall classification accuracy, achieving 93.4% accuracy in the test set when only VIS-NIR data are used to construct the classification model, up to 80.5% using only SWIR data, and up to 97.6% using both VIS-NIR and SWIR bands together.
采用可见近红外(VIS-NIR)波段(400-1000nm)和短波红外(SWIR)波段(900-1700nm)的反射率高光谱图像对与铜精炼行业相关的铜精矿进行分类研究。总共 82 个铜精矿样本被压制成 13 毫米直径的小球,通过矿物定量评估和扫描电子显微镜对其矿物组成进行了表征。这些小球中最具代表性的矿物有斑铜矿、黄铜矿、辉铜矿、砷黝铜矿和黄铁矿。三个数据库(VIS-NIR、SWIR 和 VIS-NIR-SWIR)包含了从每个小球高光谱图像的 9×9 邻域计算得到的平均反射率光谱的集合,用于训练分类模型。本工作中测试的分类模型是线性判别分类器和两个非线性分类器,即二次判别分类器和精细最近邻分类器(FKNNC)。结果表明,VIS-NIR 和 SWIR 波段的联合使用可以准确地对仅在矿物成分上存在细微差异的类似铜精矿进行分类。具体来说,在三种测试的分类模型中,FKNNC 在总体分类准确性方面表现最佳,仅使用 VIS-NIR 数据构建分类模型时,测试集的准确率达到 93.4%,仅使用 SWIR 数据时准确率达到 80.5%,同时使用 VIS-NIR 和 SWIR 波段时准确率达到 97.6%。