School of Materials Science and Engineering, Beihang University, Beijing, China.
Tianmushan Laboratory, Xixi Octagon City, Hangzhou, China.
Sci Adv. 2023 May 5;9(18):eadf8602. doi: 10.1126/sciadv.adf8602.
The extraordinary work hardening ability and fracture toughness of the face-centered cubic (fcc) high-entropy alloys render them ideal candidates for many structural applications. Here, the deformation and failure mechanisms of an equiatomic CrCoNi medium-entropyalloy (MEA) were investigated by powerful laser-driven shock experiments. Multiscale characterization demonstrates that profuse planar defects including stacking faults, nanotwins, and hexagonal nanolamella were generated during shock compression, forming a three-dimensional network. During shock release, the MEA fractured by strong tensile deformation and numerous voids was observed in the vicinity of the fracture plane. High defect populations, nanorecrystallization, and amorphization were found adjacent to these areas of localized deformation. Molecular dynamics simulations corroborate the experimental results and suggest that deformation-induced defects formed before void nucleation govern the geometry of void growth and delay their coalescence. Our results indicate that the CrCoNi-based alloys are impact resistant, damage tolerant, and potentially suitable in applications under extreme conditions.
面心立方(fcc)高熵合金具有非凡的加工硬化能力和断裂韧性,使其成为许多结构应用的理想候选材料。在这里,通过强大的激光驱动冲击实验研究了等原子 CrCoNi 中熵合金(MEA)的变形和失效机制。多尺度特性表明,在冲击压缩过程中会产生大量的面缺陷,包括层错、纳米孪晶和六方纳米层片,形成三维网络。在冲击释放过程中,在断裂面附近观察到 MEA 通过强烈的拉伸变形和大量的空穴而断裂。在这些局部变形区域附近发现了高密度的缺陷、纳米再结晶和非晶化。分子动力学模拟证实了实验结果,并表明在空洞形核之前形成的变形诱导缺陷控制着空洞生长的几何形状,并延迟了它们的聚合。我们的研究结果表明,基于 CrCoNi 的合金具有抗冲击性、耐损伤性,并且在极端条件下的应用中具有潜在的适用性。