Department of Chemical and Environmental Technology, ESCET, Universidad Rey Juan Carlos, C/ Tulipán s/n, 28933 Móstoles, Madrid, Spain.
Department of Chemical and Environmental Technology, ESCET, Universidad Rey Juan Carlos, C/ Tulipán s/n, 28933 Móstoles, Madrid, Spain.
Sci Total Environ. 2023 Aug 10;885:163963. doi: 10.1016/j.scitotenv.2023.163963. Epub 2023 May 4.
The increase in efficiency achieved by UV LED devices has led to a compelling increase in research reports on UV LED water treatment for consumption in the past few years. This paper presents an in-depth review based on recent studies on the suitability and performance of UV LED-driven processes for water disinfection. The effect of different UV wavelengths and their combinations was analysed for the inactivation of various microorganisms and the inhibition of repair mechanisms. Whereas 265 nm UVC LED present a higher DNA damaging potential, 280 nm radiation is reported to repress photoreactivation and dark repair. No synergistic effects have been proved to exist when coupling UVB + UVC whereas sequential UVA-UVC radiation seemed to enhance inactivation. Benefits of pulsed over continuous radiation in terms of germicidal effects and energy consumption were also analysed, but with inconclusive results. However, pulsed radiation may be promising for improving thermal management. As a challenge, the use of UV LED sources introduces significant inhomogeneities in the light distribution, pushing for the development of adequate simulation methods to ensure that the minimum target dose required for the target microbes is achieved. Concerning energy consumption, selecting the optimal wavelength of the UV LED needs a compromise between the quantum efficiency of the process and the electricity-to-photon conversion. The expected development of the UV LED industry in the next few years points to UVC LED as a promising technology for water disinfection at a large scale that could be competitive in the market in the near future.
UV LED 器件效率的提高促使过去几年中关于 UV LED 水处理的研究报告数量显著增加,这些研究报告可用于消费。本文基于最近关于 UV LED 驱动工艺在水消毒方面的适用性和性能的研究,进行了深入的综述。分析了不同 UV 波长及其组合对各种微生物失活和修复机制抑制的影响。虽然 265nm UVC LED 具有更高的 DNA 损伤潜力,但据报道,280nm 辐射会抑制光复活和暗修复。当耦合 UVB+UVC 时,没有证明存在协同效应,而连续的 UVA-UVC 辐射似乎会增强失活作用。还分析了脉冲辐射相对于连续辐射在杀菌效果和能耗方面的优势,但结果尚无定论。然而,脉冲辐射在改善热管理方面可能具有很大的前景。作为一个挑战,UV LED 光源的使用会在光分布上引入显著的不均匀性,这需要开发适当的模拟方法来确保达到目标微生物所需的最小目标剂量。关于能耗,选择 UV LED 的最佳波长需要在工艺的量子效率和电能到光子的转换之间进行权衡。未来几年 UV LED 行业的预期发展表明,UVC LED 是一种很有前途的大规模水消毒技术,在不久的将来可能会在市场上具有竞争力。