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通过一种简单且无金属的催化体系将5-羟甲基糠醛转化为2,5-呋喃二甲酸。

Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system.

作者信息

Wang Xue, Guo Xinyuan, Wang Xinmei, Li Chi, Wang Shanjun, Li Han, Gao Yan'an, Li Yiying, Wang Jinhui, Xu Huanjun

机构信息

Department of Medicinal Chemistry and Natural Medicine Chemistry, College of Pharmacy, Harbin Medical University Harbin China

School of Science, Qiongtai Normal University Haikou 571127 China.

出版信息

RSC Adv. 2023 May 10;13(20):13819-13823. doi: 10.1039/d3ra01104f. eCollection 2023 May 2.

DOI:10.1039/d3ra01104f
PMID:37181510
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10170353/
Abstract

A simple and metal-free catalytic system composed of NaOBu/DMF and an O balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfactory to excellent yield by this catalytic system.

摘要

由NaOBu/DMF和一个氧气球组成的简单且无金属的催化体系能有效地将5-羟甲基糠醛（5-HMF）转化为呋喃-2,5-二甲酸，产率为80.85%。该催化体系还能将5-HMF类似物和各种类型的醇以令人满意至优异的产率转化为它们相应的酸。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f3f/10170353/34fc03769de7/d3ra01104f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f3f/10170353/34fc03769de7/d3ra01104f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f3f/10170353/34fc03769de7/d3ra01104f-s1.jpg

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How Catalysts and Experimental Conditions Determine the Selective Hydroconversion of Furfural and 5-Hydroxymethylfurfural.催化剂和实验条件如何决定糠醛和5-羟甲基糠醛的选择性加氢转化
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