Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali, Università del Salento, Prov.le Lecce-Monteroni, I-73100 Lecce, Italy.
Dipartimento di Farmacia-Scienze del Farmaco, Università deli Studi di Bari "Aldo Moro", Consorzio C.I.N.M.P.I.S., Via Orabona, 4, I-70125 Bari, Italy.
Org Biomol Chem. 2023 Jun 28;21(25):5164-5170. doi: 10.1039/d3ob00596h.
Pd-catalyzed alkoxycarbonylation of aryl iodides has been explored, for the first time, in phosphonium-based deep eutectic solvents under gas-free conditions, by using Mo(CO) as the CO source. The method allows the preparation of ethylene glycol and glycerol esters in high yields (up to 99%), short reaction times and under mild reaction conditions with a very low catalyst loading (0.5 mol%).
钯催化的芳基碘代物的烷氧基羰基化反应，首次在无气体条件下，在基于鏻的深共熔溶剂中，以 Mo(CO) 作为 CO 源进行了探索。该方法可以在非常低的催化剂负载量（0.5 mol%）下，以高收率（高达 99%）、短反应时间和温和的反应条件，制备乙二醇和甘油酯。
