关于2-羟乙基呋喃-5-羧酸（MHEF）和双（2-羟乙基）呋喃-2,5-二羧酸酯（BHEF）的环境友好合成
On the Environmentally Friendly Synthesis of 2-Hydroxyethyl Furan-5-Carboxylic Acid (MHEF) and bis(2-Hydroxyethyl) Furan-2,5-Dicarboxylate (BHEF).
作者信息
Raboni Francesco, Oliveri Andrea, Rocca Valeria Marisa, Moni Lisa, Kumar Virender, Varrone Cristiano, Pellis Alessandro
机构信息
Dipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Via Dodecaneso 31, 16146, Genova, Italy.
Department of Chemistry and Bioscience, Aalborg Universitet, Fredrik Bajers Vej 7H, 9220, Aalborg Øst, Denmark.
出版信息
ChemistryOpen. 2025 Jan 28:e202400507. doi: 10.1002/open.202400507.
To better understand how the biocatalyzed depolymerization of polyesters works, model molecules are needed to develop activity assays and determine enzymatic kinetic parameters. In this communication the chemical synthesis and characterization of 2-hydroxyethyl furan-5-carboxylic acid and bis(2-hydroxyethyl) furan-2,5-dicarboxylates as potential model molecules to further study the enzymatic depolymerization of poly(ethylene furanoate) was investigated.
为了更好地理解聚酯的生物催化解聚过程是如何进行的，需要模型分子来开发活性测定方法并确定酶动力学参数。在本通讯中，对2-羟乙基呋喃-5-羧酸和双（2-羟乙基）呋喃-2,5-二羧酸酯作为潜在模型分子的化学合成及表征进行了研究，以进一步研究聚（乙烯呋喃酸酯）的酶促解聚。
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