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化学法制备的 MgO 纳米粒子/HDPE 复合材料的辐射衰减性能。

Radiation attenuation properties of chemically prepared MgO nanoparticles/HDPE composites.

机构信息

Physics Department, Faculty of Science, Alexandria University, 21511, Alexandria, Egypt.

Department of Basic and Applied Sciences, Faculty of Engineering, Arab Academy for Science, Technology and Maritime Transport, Alexandria, Egypt.

出版信息

Sci Rep. 2023 Jun 19;13(1):9945. doi: 10.1038/s41598-023-37088-y.

Abstract

Sheets of high-density polyethylene (HDPE) loaded with magnesium oxide in micro and nano were synthesized with different weight percentages of micro-MgO (0,5,10,20 and 30% by weight) and nano-MgO (5 and 30%) and shaped in form of disc and dog bone shape. The morphological, mechanical, and attenuation characteristics of each concentration were determined. The linear attenuation coefficients (LAC) of the prepared discs were calculated using a well-calibrated scintillation detector and five standard gamma-ray point sources (Am, Ba, Cs, Co and Eu). The LAC was theoretically calculated for HDPE/micro-MgO composites using XCOM software. A good agreement between the theoretical and experimental results was observed. The comparison between micro and nano-MgO as a filler in HDPE was evaluated. The results proved that the loaded nano-MgO in different proportions of HDPE produced greater attenuation coefficients than its micro counterpart. The addition of nano MgO with different weight percentage led to a significant improvement in the mechanical properties of HDPE, the ultimate force and ultimate stress increased as the concentration of nano MgO increased, and the young modulus of HDPE also increased with increasing concentration of micro and nano MgO.

摘要

用不同重量百分比的微米氧化镁(0、5、10、20 和 30%)和纳米氧化镁(5 和 30%)合成了具有高密度聚乙烯(HDPE)薄片,并将其微纳米化。将其模压成圆盘和狗骨形状。确定了每种浓度的形态、机械和衰减特性。使用经过良好校准的闪烁探测器和五个标准伽马射线点源(Am、Ba、Cs、Co 和 Eu)计算了制备的圆盘的线性衰减系数(LAC)。使用 XCOM 软件理论计算了 HDPE/微米氧化镁复合材料的 LAC。观察到理论和实验结果之间的良好一致性。评估了微纳米氧化镁作为 HDPE 填料的比较。结果表明,HDPE 中负载不同比例的纳米氧化镁产生的衰减系数大于其微米对应物。添加不同重量百分比的纳米 MgO 可显著提高 HDPE 的机械性能,随着纳米 MgO 浓度的增加,极限力和极限应力增加,随着微纳米 MgO 浓度的增加,HDPE 的杨氏模量也增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22c7/10279736/19f0c3bf20d4/41598_2023_37088_Fig1_HTML.jpg

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