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用于通过反向裂纹扩展实现可编程粘附的超材料粘合剂。

Metamaterial adhesives for programmable adhesion through reverse crack propagation.

作者信息

Hwang Dohgyu, Lee Chanhong, Yang Xingwei, Pérez-González Jose M, Finnegan Jason, Lee Bernard, Markvicka Eric J, Long Rong, Bartlett Michael D

机构信息

Department of Mechanical Engineering, Soft Materials and Structures Lab, Virginia Tech, Blacksburg, VA, USA.

Macromolecules Innovation Institute, Virginia Tech, Blacksburg, VA, USA.

出版信息

Nat Mater. 2023 Aug;22(8):1030-1038. doi: 10.1038/s41563-023-01577-2. Epub 2023 Jun 22.

DOI:10.1038/s41563-023-01577-2
PMID:37349397
Abstract

Adhesives are typically either strong and permanent or reversible with limited strength. However, current strategies to create strong yet reversible adhesives needed for wearable devices, robotics and material disassembly lack independent control of strength and release, require complex fabrication or only work in specific conditions. Here we report metamaterial adhesives that simultaneously achieve strong and releasable adhesion with spatially selectable adhesion strength through programmed cut architectures. Nonlinear cuts uniquely suppress crack propagation by forcing cracks to propagate backwards for 60× enhancement in adhesion, while allowing crack growth in the opposite direction for easy release and reusability. This mechanism functions in numerous adhesives on diverse substrates in wet and dry conditions and enables highly tunable adhesion with independently programmable adhesion strength in two directions simultaneously at any location. We create these multifunctional materials in a maskless, digital fabrication framework to rapidly customize adhesive characteristics with deterministic control for next-generation adhesives.

摘要

粘合剂通常要么粘性强且持久,要么强度有限但可逆转。然而,目前用于可穿戴设备、机器人技术和材料拆解所需的强而可逆粘合剂的策略,缺乏对强度和释放的独立控制,需要复杂的制造工艺,或者仅在特定条件下才能发挥作用。在此,我们报告了一种超材料粘合剂,它通过编程切割结构同时实现了具有空间可选择粘附强度的强粘附性和可释放粘附性。非线性切割通过迫使裂纹向后传播来独特地抑制裂纹扩展,从而使粘附力增强60倍,同时允许裂纹沿相反方向生长以便于释放和重复使用。这种机制在各种干湿条件下的不同基材上的众多粘合剂中都能发挥作用,并能够在任何位置同时在两个方向上实现具有独立可编程粘附强度的高度可调粘附性。我们在无掩模数字制造框架中创建这些多功能材料,以便通过确定性控制快速定制粘合剂特性,用于下一代粘合剂。

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