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用于从水介质中高效去除铜(II)和镉(II)离子的FeO/方沸石纳米复合材料的简便合成与表征

Facile synthesis and characterization of FeO/analcime nanocomposite for the efficient removal of Cu(II) and Cd(II) ions from aqueous media.

作者信息

Algethami Faisal K, Al-Wasidi Asma S, Al-Farraj Eida S, Katouah Hanadi A, Abdelrahman Ehab A

机构信息

Department of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 11623, Saudi Arabia.

Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia.

出版信息

Discov Nano. 2023 Apr 25;18(1):70. doi: 10.1186/s11671-023-03848-y.

Abstract

In the water purification field, heavy metal pollution is a problem that causes severe risk aversion. This study aimed to examine the disposal of cadmium and copper ions from aqueous solutions by a novel FeO/analcime nanocomposite. A field emission scanning electron microscope (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction were used to characterize the synthesized products. The FE-SEM images showed that the analcime and FeO samples consist of polyhedral and quasi-spherical shapes with average diameters of 923.28 and 28.57 nm, respectively. Besides, the FeO/analcime nanocomposite consists of polyhedral and quasi-spherical shapes with average diameters of 1100.00 nm. The greatest uptake capability of the FeO/analcime nanocomposite toward the copper and cadmium ions is 176.68 and 203.67 mg/g, respectively. The pseudo-second-order kinetic model and Langmuir equilibrium isotherm best describe the uptake of copper and cadmium ions using the FeO/analcime nanocomposite. The uptake of copper and cadmium ions using the FeO/analcime nanocomposite is exothermic and chemical in nature.

摘要

在水净化领域,重金属污染是一个引发严重风险规避的问题。本研究旨在考察一种新型FeO/方沸石纳米复合材料对水溶液中镉离子和铜离子的处理效果。采用场发射扫描电子显微镜(FE-SEM)、傅里叶变换红外光谱(FT-IR)和X射线衍射对合成产物进行表征。FE-SEM图像显示,方沸石和FeO样品分别由平均直径为923.28和28.57 nm的多面体和准球形组成。此外,FeO/方沸石纳米复合材料由平均直径为1100.00 nm的多面体和准球形组成。FeO/方沸石纳米复合材料对铜离子和镉离子的最大吸附量分别为176.68和203.67 mg/g。伪二级动力学模型和朗缪尔平衡等温线能最好地描述FeO/方沸石纳米复合材料对铜离子和镉离子的吸附过程。FeO/方沸石纳米复合材料对铜离子和镉离子的吸附在本质上是放热的且属于化学吸附。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ce3/10409969/c24a0f0d89eb/11671_2023_3848_Fig1_HTML.jpg

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