Zhang Yuxuan, Luo Jun, Zhang Hanshuo, Li Tianxiao, Xu Hongxia, Sun Yuanyuan, Gu Xueyuan, Hu Xin, Gao Bin
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, PR China.
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, PR China..
Sci Total Environ. 2022 Dec 15;852:158201. doi: 10.1016/j.scitotenv.2022.158201. Epub 2022 Aug 24.
This review focuses on the removal of heavy metals from water by three-dimensional gels with carbon nanomaterials as the main building units. It highlights the fundamental knowledge, most recent advances, and future prospects of carbon nanomaterial-assembled gels (CNAGs) as effective adsorbents for heavy metals in water. Various synthesis methods of CNAGs including template-assisted, self-assembly and other methods are systematically summarized and evaluated. Adsorption performances of CNAGs to typical cationic and anionic heavy metals, especially lead, cadmium, mercury, chromium, and arsenic, are thoroughly examined and discussed in detail. These analyses bring out that composite CNAGs constructed from carbon nanomaterials with polymers or other engineered nanoparticles are the most promising adsorbents for heavy metal removal from water. Current challenges and future research directions that are critical to the applications of CNAGs in the removal of heavy metals from contaminated water are outlined at the end of the review.
本综述聚焦于以碳纳米材料为主要构建单元的三维凝胶对水中重金属的去除。它突出了碳纳米材料组装凝胶(CNAGs)作为水中重金属有效吸附剂的基础知识、最新进展和未来前景。系统总结并评估了包括模板辅助法、自组装法等在内的各种CNAGs合成方法。详细考察并深入讨论了CNAGs对典型阳离子和阴离子重金属,特别是铅、镉、汞、铬和砷的吸附性能。这些分析表明,由碳纳米材料与聚合物或其他工程纳米粒子构建的复合CNAGs是从水中去除重金属最有前景的吸附剂。综述结尾概述了CNAGs在从受污染水中去除重金属应用中至关重要的当前挑战和未来研究方向。