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绿贻贝贝壳中壳聚糖的物理化学性质():一项比较研究。

Physicochemical Properties of Chitosan from Green Mussel Shells (): A Comparative Study.

作者信息

Kaewprachu Pimonpan, Jaisan Chalalai

机构信息

College of Maritime Studies and Management, Chiang Mai University, Samut Sakhon 74000, Thailand.

出版信息

Polymers (Basel). 2023 Jun 26;15(13):2816. doi: 10.3390/polym15132816.

Abstract

Green mussel shells () are generated in huge amounts and discarded as waste materials. Such waste may be used to produce biopolymer materials such as chitosan. The physicochemical properties of chitosan prepared from different sizes of green mussel shells (small size (CHS): ≤5.00 cm in length and big size (CHB): >5.01 cm in length) were characterized and compared with commercial chitosan (CH). Furthermore, the mechanical and physicochemical properties of the blended films were also investigated. The results of the physicochemical properties showed that CHS and CHB were quite different from CH. The degree of deacetylation of CHS, CHB, and CH was found to be 32.71%, 52.56%, and 70.42%, respectively ( < 0.05). The water- and fat-binding capacities of CH were higher than those of CHS and CHB. Structural differences between CHS, CHB, and CH were studied using Fourier transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD). Significant increases in thickness, water vapor permeability, and strength of the blended films were found when the extracted chitosan was added ( < 0.05). However, further study is needed to improve the chitosan extraction process, which can enhance the physicochemical properties of the obtained chitosan and be widely used in many industries.

摘要

绿贻贝壳大量产生并作为废料丢弃。这种废料可用于生产生物聚合物材料,如壳聚糖。对由不同尺寸绿贻贝壳制备的壳聚糖(小尺寸(CHS):长度≤5.00厘米和大尺寸(CHB):长度>5.01厘米)的物理化学性质进行了表征,并与市售壳聚糖(CH)进行了比较。此外,还研究了共混膜的力学和物理化学性质。物理化学性质结果表明,CHS和CHB与CH有很大不同。发现CHS、CHB和CH的脱乙酰度分别为32.71%、52.56%和70.42%(P<0.05)。CH的水结合能力和脂肪结合能力高于CHS和CHB。使用傅里叶变换红外光谱(FTIR)和X射线粉末衍射(XRD)研究了CHS、CHB和CH之间的结构差异。当添加提取的壳聚糖时,发现共混膜的厚度、水蒸气透过率和强度显著增加(P<0.05)。然而,需要进一步研究以改进壳聚糖提取工艺,该工艺可以提高所得壳聚糖的物理化学性质并广泛应用于许多行业。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ef1/10347266/9d6768310618/polymers-15-02816-g001.jpg

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