Kozma Michael, Acharya Bishnu, Bissessur Rabin
Department of Chemistry, University of Prince Edward Island, 550 University Avenue, Charlottetown, PE C1A 4P3, Canada.
Department of Chemical and Biological Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK S7N 5A9, Canada.
Polymers (Basel). 2022 Sep 23;14(19):3989. doi: 10.3390/polym14193989.
Crustacean shells are a sustainable source of chitin. Extracting chitin from crustacean shells is ongoing research, much of which is devoted to devising a sustainable process that yields high-quality chitin with minimal waste. Chemical and biological methods have been used extensively for this purpose; more recently, methods based on ionic liquids and deep eutectic solvents have been explored. Extracted chitin can be converted into chitosan or nanochitin. Once chitin is obtained and modified into the desired form, it can be used in a wide array of applications, including as a filler material, in adsorbents, and as a component in biomaterials, among others. Describing the extraction of chitin, synthesis of chitosan and nanochitin, and applications of these materials is the aim of this review. The first section of this review summarizes and compares common chitin extraction methods, highlighting the benefits and shortcomings of each, followed by descriptions of methods to convert chitin into chitosan and nanochitin. The second section of this review discusses some of the wide range of applications of chitin and its derivatives.
甲壳类动物的外壳是几丁质的可持续来源。从甲壳类动物外壳中提取几丁质的研究正在进行中,其中大部分致力于设计一种可持续的工艺,以产生高质量的几丁质且废弃物最少。化学和生物学方法已广泛用于此目的;最近,基于离子液体和低共熔溶剂的方法也已得到探索。提取的几丁质可转化为壳聚糖或纳米几丁质。一旦获得几丁质并将其改性成所需形式,它就可用于广泛的应用中,包括作为填充材料、吸附剂以及生物材料的成分等。描述几丁质的提取、壳聚糖和纳米几丁质的合成以及这些材料的应用是本综述的目的。本综述的第一部分总结并比较了常见的几丁质提取方法,突出了每种方法的优点和缺点,随后描述了将几丁质转化为壳聚糖和纳米几丁质的方法。本综述的第二部分讨论了几丁质及其衍生物的一些广泛应用。