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掺杂富勒烯和其他碳基纳米材料的共轭有机材料的折射特性。

Refractive Properties of Conjugated Organic Materials Doped with Fullerenes and Other Carbon-Based Nano-Objects.

作者信息

Kamanina Natalia

机构信息

Vavilov State Optical Institute, Kadetskaya Liniya V.O. 5/2, 199053 St. Petersburg, Russia.

Department of Photonics, St. Petersburg Electrotechnical University ("LETI"), ul. Prof. Popova 5, 197376 St. Petersburg, Russia.

出版信息

Polymers (Basel). 2023 Jun 26;15(13):2819. doi: 10.3390/polym15132819.

Abstract

Due to the high demand for optoelectronics for use in new materials and processes, as well as the search for their modeling properties, the expansion of the functionality of modified materials using nanotechnology methods is relevant and timely. In the current paper, a specific nanotechnology approach is shown to increase the refractive and photoconductive parameters of the organic conjugated materials. The sensitization process, along with laser treatment, are presented in order to improve the basic physical-chemical properties of laser, solar energy, and general photonics materials. Effective nanoparticles, such as fullerenes, shungites, reduced graphene oxides, carbon nanotubes, etc., are used in order to obtain the bathochromic shift, increase the laser-induced change in the refractive index, and amplify the charge carrier mobility of the model matrix organics sensitized with these nanoparticles. The four-wave mixing technique is applied to test the main refractive characteristics of the studied materials. Volt-current measurements are used to estimate the increased charge carrier mobility. The areas of application for the modified nanostructured plastic matrixes are discussed and extended, while also taking into account the surface relief.

摘要

由于对用于新材料和新工艺的光电子器件有很高的需求,以及对其建模特性的探索,利用纳米技术方法扩展改性材料的功能既相关又及时。在当前论文中,展示了一种特定的纳米技术方法来提高有机共轭材料的折射和光电导参数。为了改善激光、太阳能和一般光子学材料的基本物理化学性质,介绍了敏化过程以及激光处理。使用富勒烯、水碳质、还原氧化石墨烯、碳纳米管等有效纳米粒子,以获得红移、增加激光诱导的折射率变化,并放大用这些纳米粒子敏化的模型基质有机物的电荷载流子迁移率。应用四波混频技术测试所研究材料的主要折射特性。使用伏安测量来估计电荷载流子迁移率的增加。讨论并扩展了改性纳米结构塑料基质的应用领域,同时也考虑了表面起伏。

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