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紫外光固化增强型有机长余辉发光材料

UV-Curing-Enhanced Organic Long-Persistent Luminescence Materials.

作者信息

Liang Yimeng, Liu Man, Wang Tiantian, Mao Jiayi, Wang Lichang, Liu Dongzhi, Wang Tianyang, Hu Wenping

机构信息

Tianjin Key Laboratory of Molecular Optoelectronic Science (TJ-MOS), Key Laboratory of Organic Integrated Circuits of Ministry of Education, Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China.

Department of Chemistry and Biochemistry and the Materials Technology Center, Southern Illinois University, Carbondale, IL, 62901, USA.

出版信息

Adv Mater. 2023 Nov;35(44):e2304820. doi: 10.1002/adma.202304820. Epub 2023 Sep 22.

Abstract

Amorphous organic long-persistent luminescence materials (OLPLMs) can realize simpler solution processing and large-area uniform luminescence, where the luminescent properties are significantly influenced by the rigid environment. However, research on utilizing the rigidity to promote long-persistent luminescence (LPL) properties of amorphous OLPLMs is still relatively rare due to the lack of an unambiguous and effective strategy to construct the rigid environment. Here, a universal strategy is proposed to enhance the LPL performance of organic host-guest doping systems by UV curing, which utilizes the rigid environment constructed by UV curing to promote the interaction between host and guest, thus inducing a generation of materials with highly efficient LPL performance. This solution-processable, large-area, and "easy-to-realize" material fabrication strategy can make amorphous OLPLMs show broader application prospects in some fields, such as anti-counterfeiting, nondestructive detection, and pattern marking or indication.

摘要

无定形有机长余辉发光材料(OLPLMs)能够实现更简便的溶液加工以及大面积均匀发光,其发光性能会受到刚性环境的显著影响。然而,由于缺乏明确有效的构建刚性环境的策略,利用刚性来提升无定形OLPLMs的长余辉发光(LPL)性能的研究仍然相对较少。在此,提出了一种通过紫外光固化来增强有机主体 - 客体掺杂体系LPL性能的通用策略,该策略利用紫外光固化构建的刚性环境来促进主体与客体之间的相互作用,从而诱导生成具有高效LPL性能的材料。这种可溶液加工、大面积且“易于实现”的材料制备策略能够使无定形OLPLMs在防伪、无损检测以及图案标记或指示等一些领域展现出更广阔的应用前景。

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