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用于评估天然染料敏化太阳能电池性能的纳米工程二氧化钛。

Nanoengineering TiO for evaluating performance in dye sensitized solar cells with natural dyes.

作者信息

Khan Mohd Jahir, Ahirwar Ankesh, Sirotiya Vandana, Rai Anshuman, Varjani Sunita, Vinayak Vandana

机构信息

Diatom Nanoengineering and Metabolism Laboratory (DNM), School of Applied Science, Dr. Harisingh Gour Central University Sagar MP 470003 India

School of Engineering, Department of Biotechnology, Maharishi Markendeshwar University Ambala Haryana 133203 India.

出版信息

RSC Adv. 2023 Jul 26;13(32):22630-22638. doi: 10.1039/d3ra02927a. eCollection 2023 Jul 19.

Abstract

The current study employs nanoengineering diatom and TiO NPs to form diatom-Si-TiO nanoengineered structures to fabricate a dye sensitized solar cell (DSSC) (-DSSC). This was characterized and spin coated on a Fluorine-doped Tin Oxide (FTO) anode plate. The counter cathode was prepared by spin coating graphene oxide on a FTO glass plate and using Lugol's iodine as an electrolyte. The power density of -DSSC was estimated with different natural dyes in comparison to conventional photosensitive ruthenium dye. It was found that the natural dyes extracted from plants and microalgae show significant power efficiencies in DSSC. The percentage efficiency of maximum power densities (PD) of -DSSC obtained with photosensitive dyes were 9.4% with synthetic ruthenium dye (control) and 7.19% > 4.08% > 0.72% > 0.58% > 0.061% from natural dyes found in (astaxanthin) > (anthocyanin) > (anthocyanin) > (anthocyanin) > (betalains), respectively. Among all the natural dyes used, the PD for the control ruthenium dye was 6.164 mW m followed by the highest in astaxanthin natural dye from (5.872 mW m). Overall, the use of natural dye -DSSC makes the fuel cell low cost and an alternative to conventional expensive, metal and synthetic dyes.

摘要

当前的研究采用纳米工程硅藻和二氧化钛纳米颗粒来形成硅藻-硅-二氧化钛纳米工程结构,以制造染料敏化太阳能电池(DSSC)(-DSSC)。对其进行了表征,并旋涂在氟掺杂氧化锡(FTO)阳极板上。通过在FTO玻璃板上旋涂氧化石墨烯并使用卢戈氏碘作为电解质来制备对电极阴极。与传统的光敏钌染料相比,用不同的天然染料估计了-DSSC的功率密度。结果发现,从植物和微藻中提取的天然染料在DSSC中显示出显著的功率效率。用光敏染料获得的-DSSC最大功率密度(PD)的效率百分比,合成钌染料(对照)为9.4%,而在(虾青素)>(花青素)>(花青素)>(花青素)>(甜菜碱)中发现的天然染料分别为7.19%>4.08%>0.72%>0.58%>0.061%。在所有使用的天然染料中,对照钌染料的PD为6.164 mW m,其次是来自(5.872 mW m)的虾青素天然染料中的最高值。总体而言,使用天然染料-DSSC使燃料电池成本低廉,成为传统昂贵的金属和合成染料的替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1553/10369046/c966fd441813/d3ra02927a-f1.jpg

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