Munoz Alejandro, Schmidt Jacob, Suffet I H Mel, Tsai Candace Su-Jung
Department of Environmental Health Sciences, Fielding School of Public Health, University of California-Los Angeles, Los Angeles, California 90095-1735, United States.
Samueli School of Engineering, University of California-Los Angeles, Los Angeles, California 90095-1735, United States.
J Chem Health Saf. 2023 Jun 22;30(4):182-192. doi: 10.1021/acs.chas.3c00013. eCollection 2023 Jul 24.
Carbon dioxide laser cutters are used to cut and engrave on various types of materials, including metals, wood, and plastics. Although many are equipped with fume extractors for removing airborne substances generated during laser cutting, gases and particulate matter can be released upon opening the lid after completion. This study focused on investigating laser cutting acrylic sheets and associated emissions. Real-time instruments were utilized to monitor both particulate concentrations and size distributions, while the patented Tsai diffusion sampler was used to collect particulate samples on a polycarbonate membrane and transmission electron microscopy (TEM) grid. Identification of released gases consisted of the use of gas sampling with Teflon gas bags followed by analysis using gas chromatography-mass spectrometry (GC-MS). A portable ambient infrared air analyzer was used to quantify the concentrations of the chemicals released by laser cutting activities. The results of the study found that a significant concentration of particulate matter, including nanoplastic particles ranging 15.4-86 nm in particle sizes, and microplastics with agglomerates were released each time the laser cutter lid was opened and were observed to gradually increase in concentration for a period of at least 20 min after the completion of a cut. The GC-MS gaseous samples primarily contained methyl methacrylate at a low level close to the detection limit of the infrared air analyzer.
二氧化碳激光切割机用于切割和雕刻各种类型的材料,包括金属、木材和塑料。尽管许多切割机配备了烟雾抽取器以去除激光切割过程中产生的空气中的物质,但切割完成后打开盖子时仍会释放气体和颗粒物。本研究重点调查激光切割丙烯酸板及相关排放物。使用实时仪器监测颗粒物浓度和粒径分布,同时使用专利的蔡氏扩散采样器在聚碳酸酯膜和透射电子显微镜(TEM)网格上采集颗粒物样本。对释放气体的鉴定包括使用特氟龙气袋进行气体采样,然后使用气相色谱 - 质谱联用仪(GC - MS)进行分析。使用便携式环境红外空气分析仪对激光切割活动释放的化学物质浓度进行定量。研究结果发现,每次打开激光切割机盖子时都会释放出大量颗粒物,包括粒径在15.4 - 86纳米范围内的纳米塑料颗粒以及带有团聚物的微塑料,并且在切割完成后的至少20分钟内观察到其浓度逐渐增加。GC - MS气态样本主要含有甲基丙烯酸甲酯,其含量较低,接近红外空气分析仪的检测限。