Zhu Neng, Hong Yu, Cai Yunkai, Dong Fei, Song Jie
School of Automotive and Transportation Engineering, Wuhan University of Science and Technology, Wuhan 430081, China.
School of Naval Architecture, Ocean and Energy Power Engineering, Wuhan University of Technology, Wuhan 430063, China.
Materials (Basel). 2023 Jul 12;16(14):4969. doi: 10.3390/ma16144969.
Compared to diesel, liquefied natural gas (LNG), often used as an alternative fuel for marine engines, comes with significant advantages in reducing emissions of particulate matter (PM), SO, CO, and other pollutants. Promoting the use of LNG is of great significance for achieving carbon peaking and neutrality worldwide, as well as improving the energy structure. However, compared to diesel engines, medium- and high-speed marine LNG engines may produce higher methane (CH) emissions and also have nitrogen oxide (NO) emission issues. For the removal of CH and NO from the exhaust of marine LNG engines, the traditional technical route of combining a methane oxidation catalyst (MOC) and an HN selective catalytic reduction system (NH-SCR) will face problems, such as low conversion efficiency and high operation cost. In view of this, the technology of non-thermal plasma (NTP) combined with CH-SCR is proposed. However, the synergistic mechanism between NTP and catalysts is still unclear, which limits the optimization of an NTP-CH-SCR system. This article summarizes the synergistic mechanism of NTP and catalysts in the integrated treatment process of CH and NO, including experimental analysis and numerical simulation. And the relevant impact parameters (such as electrode diameter, electrode shape, electrode material, and barrier material, etc.) of NTP reactor energy optimization are discussed. The work of this paper is of great significance for guiding the high-efficiency removal of CH and NO for an NTP-CH-SCR system.
与柴油相比,经常用作船用发动机替代燃料的液化天然气(LNG)在减少颗粒物(PM)、SO、CO和其他污染物排放方面具有显著优势。推广使用LNG对于在全球实现碳达峰和碳中和以及改善能源结构具有重要意义。然而,与柴油发动机相比,中高速船用LNG发动机可能会产生更高的甲烷(CH)排放,并且还存在氮氧化物(NO)排放问题。对于从船用LNG发动机排气中去除CH和NO,传统的将甲烷氧化催化剂(MOC)和氨选择性催化还原系统(NH-SCR)相结合的技术路线将面临转化率低和运行成本高等问题。鉴于此,提出了非热等离子体(NTP)与CH-SCR相结合的技术。然而,NTP与催化剂之间的协同作用机制仍不明确,这限制了NTP-CH-SCR系统的优化。本文总结了NTP与催化剂在CH和NO综合处理过程中的协同作用机制,包括实验分析和数值模拟。并讨论了NTP反应器能量优化的相关影响参数(如电极直径、电极形状、电极材料和屏障材料等)。本文的工作对于指导NTP-CH-SCR系统高效去除CH和NO具有重要意义。