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在不同金属纳米颗粒存在的情况下,用具有不同官能团的聚合材料处理后棉织物和聚酯织物功能性能的增强。

Enhancement of the Functional Performance of Cotton and Polyester Fabrics upon Treatment with Polymeric Materials Having Different Functional Groups in the Presence of Different Metal Nanoparticles.

作者信息

Abd El-Aziz Eman, Zayed Menna, Mohamed Amina L, Hassabo Ahmed G

机构信息

Textile Printing, Dyeing and Finishing Department, Faculty of Applied Arts, Benha University, Benha P.O. Box 15123, Egypt.

National Research Centre (Scopus Affiliation ID 60014618), Textile Research and Technology Institute, Pretreatment, and Finishing of Cellulose-Based Fibres Department, 33 El-Behouth St. (Former El-Tahrir Str.), Dokki, Giza P.O. Box 12622, Egypt.

出版信息

Polymers (Basel). 2023 Jul 14;15(14):3047. doi: 10.3390/polym15143047.

Abstract

This work examined the functional properties of three different treated fabrics, cotton, polyester, and cotton/polyester, with different polymeric materials (polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC), or chitosan) in the presence and absence of two synthesized metal nanoparticles to impart and enhance fabric properties. Both metal nanoparticles (silver nanoparticle (AgNPs) and Zinc oxide nanoparticles (ZnONPs)) were synthesized using Leaves and characterized using different techniques. The different treated fabrics were dyed with Reactive Dye (Syozol red k-3BS) and evaluated for their color strength, fastness properties, ultraviolet protection, antimicrobial activity, and mechanical properties. Results showed that treatment with polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC), or chitosan enhances the functionality of all fabrics, with improved color strength, UV protection, and antimicrobial properties. Additionally, mechanical properties were slightly increased due to the creation of a thin film on the fabric surface. All dyed treated fabrics showed good ultraviolet protection and antimicrobial properties. The K/S of all treated textiles including nanoparticles and polymers was marginally greater than that of the treated materials without polymers. The UPF values demonstrate that the three investigated polymers and both metal nanoparticles enhance the fabrics' ability to block UV radiation and shield people's skin from its damaging effects. All treated textiles had UPF values that are higher than those of untreated textiles. Further research demonstrates that ZnONP-treated textiles exhibited greater UPF values than AgNP-treated textiles when the polymer component was present. Antibacterial examination demonstrated that treated materials had robust microbial resistance. This resistance is diminished by washing, but still prevents bacterial growth more effectively than untreated textiles.

摘要

本研究考察了三种不同处理的织物(棉、聚酯和棉/聚酯)在有和没有两种合成金属纳米颗粒存在的情况下,与不同聚合物材料(聚乙烯醇(PVA)、羧甲基纤维素(CMC)或壳聚糖)结合后的功能特性,以赋予和增强织物性能。两种金属纳米颗粒(银纳米颗粒(AgNPs)和氧化锌纳米颗粒(ZnONPs))均采用树叶合成,并使用不同技术进行表征。将不同处理的织物用活性染料(Syozol红k - 3BS)染色,并对其色强度、色牢度、紫外线防护、抗菌活性和机械性能进行评估。结果表明,用聚乙烯醇(PVA)、羧甲基纤维素(CMC)或壳聚糖处理可增强所有织物的功能,提高色强度、紫外线防护和抗菌性能。此外,由于在织物表面形成了一层薄膜,机械性能略有提高。所有染色处理过的织物都表现出良好的紫外线防护和抗菌性能。包括纳米颗粒和聚合物在内的所有处理过的纺织品的K/S值略高于未添加聚合物的处理材料。UPF值表明,所研究的三种聚合物和两种金属纳米颗粒均能增强织物阻挡紫外线辐射的能力,保护人们的皮肤免受其伤害。所有处理过的纺织品的UPF值均高于未处理的纺织品。进一步研究表明,当存在聚合物成分时,ZnONP处理的纺织品比AgNP处理的纺织品表现出更高的UPF值。抗菌检测表明,处理过的材料具有较强的抗微生物能力。这种抗性在洗涤后会降低,但仍比未处理的纺织品更有效地阻止细菌生长。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/883f/10385963/60ccf8ea53af/polymers-15-03047-sch001.jpg

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