Novel glass-based membranes for Cu adsorption: From alkali activation to sintering.

A porous membrane was developed through alkali activation of pharmaceutical boro-alumino-silicate glass powders suspended in diluted NaOH and KOH aqueous solutions (2.5 M). A consolidated porous structure was obtained by the binding of unreacted particles mediated by a surface gel, developed upon drying of the suspensions and their curing at 40 °C for 14 days. The binding phase was sufficiently stable to resist immersion in boiling water and in acidic solutions. Copper adsorption tests were carried out under acidic pH, immersing the membranes in a Cu(NO) solution for different periods of time. To determine the effect of surface washing on capture of copper ions, adsorption experiments with washed and unwashed membranes were also carried out, at varying pH. It was determined that the adsorption kinetics follow the pseudo-second-order kinetic model. The main adsorption mechanism observed is the electrostatic interaction between the negative surface charge of the washed membrane and the Cu ions present in solution. An adsorption higher than 60% was observed at pH = 5, while at pH = 2 the efficiency decreased due to the presence of HO ions. To ensure immobilization of copper, the membranes were densified by viscous flow sintering at a moderate temperature (700 °C). Leaching tests on membranes demonstrated the efficiency of the process in terms of copper ions immobilization.