Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates.

作者信息

Cai Lu-Yu, Song Xiu-Qing, Wang Kuo, Zhang Yue, Zhao Hong-Wu

机构信息

College of Life Science and Bio-engineering, Beijing University of Technology, Beijing 100124, P. R. China.

Large-scale Instruments and Equipments Sharing Platform, Beijing University of Technology, Beijing 100124, P. R. China.

出版信息

Org Biomol Chem. 2023 Aug 16;21(32):6556-6564. doi: 10.1039/d3ob00968h.

Under the catalysis of Pd(OAc)/dppf/NaCO, the decarboxylative 1,4-addition reaction of benzofuran-based azadienes with allyl phenyl carbonates took place easily and delivered the desired products in reasonable chemical yields. The chemical structure of the target compounds was clearly identified by single crystal X-ray structural analysis.