Slezak A, Turczynski B
Biophys Chem. 1986 Jul;24(2):173-8. doi: 10.1016/0301-4622(86)80011-4.
The presented modification of the transport equations of Kedem-Katchalsky resulted in the introduction of (omega s/omega) and omega/(omega-Lp sigma[(1-sigma)C1-(1-sigma s)C2]) factors into the Kedem-Katchalsky equations. The above factors determine the influence of boundary layers on transport across the membrane. The modified Kedem-Katchalsky equations were verified for synthetic membranes and it was shown that the value of the (omega s/omega) factor depended on the type of membrane and the membrane configuration system. This modification facilitated a wider range of application of the Kedem-Katchalsky equations to systems in which the solutions were stirred or unstirred.
对凯德姆-卡察尔斯基输运方程所做的上述修正，使得（ωs/ω）和ω/（ω - Lpσ[(1 - σ)C1 - (1 - σs)C2]）这两个因子被引入到凯德姆-卡察尔斯基方程中。上述因子决定了边界层对跨膜输运的影响。针对合成膜对修正后的凯德姆-卡察尔斯基方程进行了验证，结果表明（ωs/ω）因子的值取决于膜的类型和膜构型系统。这种修正使得凯德姆-卡察尔斯基方程在溶液搅拌或未搅拌的系统中有更广泛的应用范围。
