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用于火焰传感的超宽带隙 LaO/ε-GaO p-n 异质结自供电深紫外光电二极管的综合研究

Comprehensive Study on Ultra-Wide Band Gap LaO/ε-GaO p-n Heterojunction Self-Powered Deep-UV Photodiodes for Flame Sensing.

作者信息

Xi Zhaoying, Liu Zeng, Yang Lili, Tang Kai, Li Lei, Shen Gaohui, Zhang Maolin, Li Shan, Guo Yufeng, Tang Weihua

机构信息

Innovation Center for Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.

National and Local Joint Engineering Laboratory for RF Integration and Micro-Assembly Technologies, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.

出版信息

ACS Appl Mater Interfaces. 2023 Aug 30;15(34):40744-40752. doi: 10.1021/acsami.3c07597. Epub 2023 Aug 17.

DOI:10.1021/acsami.3c07597
PMID:37592828
Abstract

Solar-blind UV photodetectors have outstanding reliability and sensitivity in flame detection without interference from other signals and response quickly. Herein, we fabricated a solar-blind UV photodetector based on a LaO/ε-GaO p-n heterojunction with a typical type-II band alignment. Benefiting from the photovoltaic effect formed by the space charge region across the junction interface, the photodetector exhibited a self-powered photocurrent of 1.4 nA at zero bias. Besides, this photodetector demonstrated excellent photo-to-dark current ratio of 2.68 × 10 under 254 nm UV light illumination and at a bias of 5 V, and a high specific detectivity of 2.31 × 10 Jones and large responsivity of 1.67 mA/W were achieved. Importantly, the LaO/ε-GaO heterojunction photodetector can rapidly respond to flames in milliseconds without any applied biases. Based on the performances described above, this novel LaO/ε-GaO heterojunction is expected to be a candidate for future energy-efficient fire detection.

摘要

日盲型紫外光电探测器在火焰探测中具有出色的可靠性和灵敏度,不受其他信号干扰且响应迅速。在此,我们基于具有典型II型能带排列的LaO/ε-GaO p-n异质结制备了一种日盲型紫外光电探测器。得益于结界面处空间电荷区形成的光伏效应,该光电探测器在零偏压下呈现出1.4 nA的自驱动光电流。此外,该光电探测器在254 nm紫外光照射和5 V偏压下表现出2.68×10的优异光暗电流比,实现了2.31×10琼斯的高比探测率和1.67 mA/W的大响应度。重要的是,LaO/ε-GaO异质结光电探测器无需任何外加偏压就能在毫秒内快速响应火焰。基于上述性能,这种新型的LaO/ε-GaO异质结有望成为未来节能火灾探测的候选材料。

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