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纳米凝胶涂层在玻璃纤维增强聚合物复合材料中的应用:海洋应用的结构、力学和热分析。

Nano-gelcoat application of glass fiber reinforced polymer composites for marine application: Structural, mechanical, and thermal analysis.

机构信息

Mechanical Engineering Department, Engineering Faculty, Harran University, Sanliurfa, Turkey.

Mechanical Engineering Department, Engineering Faculty, Harran University, Sanliurfa, Turkey.

出版信息

Mar Pollut Bull. 2023 Sep;194(Pt B):115412. doi: 10.1016/j.marpolbul.2023.115412. Epub 2023 Aug 16.

Abstract

To address the critical issue of environmental sustainability, the application of nano-gelcoat has emerged as a promising approach to extend the service life and enhance the durability of glass fiber-reinforced polymer composites (GFRPs), thereby protecting the marine environment. Despite the extensive use of GFRPs in marine structures, their performance is significantly influenced by marine environmental factors. However, despite its potential, there is a lack of research on the experimental application of nano-gelcoat. To fully understand the underlying mechanisms and optimize the performance of nano-gelcoat application, more experimental investigations are required. In the present study, the hydrothermal aging of nano-gelcoat-coated glass fiber-reinforced polymer composites was investigated. Nano TiO and nanoclay were used to enhance the performance of gelcoat. A three-month hydrothermal aging experiment was carried out in artificial seawater heated to 80 °C. Mechanical and water absorption properties of GFRPs and thermal, morphological and FTIR (Fourier transform infrared spectroscopy) properties of nano-gelcoat were investigated. An ANOVA analysis was performed to establish if the experimental results were statistically significant. The long-term aging tests showed that the addition of nano-TiO improved water resistance and maintained the mechanical properties of the composite. It also improved the melting point.

摘要

为了解决环境可持续性的关键问题,纳米凝胶涂层的应用作为一种延长玻璃纤维增强聚合物复合材料(GFRP)使用寿命和增强耐久性的方法已经出现,从而保护海洋环境。尽管 GFRP 在海洋结构中得到了广泛应用,但它们的性能受到海洋环境因素的显著影响。然而,尽管纳米凝胶涂层有很大的应用潜力,但对其实验应用的研究还很缺乏。为了充分了解其潜在机制并优化纳米凝胶涂层的性能,需要进行更多的实验研究。在本研究中,研究了纳米凝胶涂层玻璃纤维增强聚合物复合材料的湿热老化。纳米 TiO 和纳米粘土被用来增强凝胶涂层的性能。在 80°C 的人工海水中进行了为期三个月的湿热老化实验。研究了 GFRP 的机械和吸水性性能以及纳米凝胶涂层的热、形态和傅里叶变换红外光谱(FTIR)性能。进行了方差分析以确定实验结果是否具有统计学意义。长期老化试验表明,添加纳米 TiO 提高了耐水性并保持了复合材料的机械性能。它还提高了熔点。

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