One-pot synthesis of nano Zr-based metal-organic frameworks for fluorescence determination of quercetin and Hg.

In this study, a nanoscale Zr-based metal-organic framework (nano-Zr-MOF) was prepared by one-pot method using meso-tetra(4-carboxyphenyl)porphyrin as organic ligand and Zr as metal unit. The nanoscale structure endows it with excellent dispersion in water. The nano-Zr-MOF exhibited intense red fluorescence, which could be significantly quenched by the addition of quercetin, probably due to its electron-rich framework. The high selectivity for quercetin detection was verified with analogues and common ions as interfering agents. Moreover, the nano-Zr-MOF could be used as a highly selective and sensitive sensor for the detection of Hg. The detection limits for quercetin and Hg were 0.026 μM and 0.039 μM, respectively. This fluorometric method was successfully applied to detect quercetin in red wine and food samples with satisfactory recoveries ranging from 83.7-112.3% and 81.8-115.9%, respectively. The recovery in detection of Hg in lake water were ranging from 97.1-109.2%.