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基于脂肪酸谱结合单类分类法的山茶油地理来源鉴别

Geographical origin identification of camellia oil based on fatty acid profiles combined with one-class classification.

作者信息

Dou Xinjing, Wang Xuefang, Ma Fei, Yu Li, Mao Jin, Jiang Jun, Zhang Liangxiao, Li Peiwu

机构信息

Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China.

Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China; Hubei Hongshan Laboratory, Wuhan 430070, China.

出版信息

Food Chem. 2024 Feb 1;433:137306. doi: 10.1016/j.foodchem.2023.137306. Epub 2023 Sep 1.

Abstract

Geographical Indication (GI) agricultural products possess specific geographical origins and high qualities, which require an effective geographical origin traceability method for the important protective trademarks. In this study, authentication models for Changshan camellia oil were developed by fatty acid profiles and one-class classification methods including data-driven soft independent modeling of class analogy (DD-SIMCA) and one-class partial least squares (OCPLS), and compared with traditional two-class classification models. The results indicated that the prediction errors of three two-class classification models were 63.8%, 12.1%, and 65.2% for the samples out of targeted geographical origins, respectively. By contrast, the one-class classification models could completely differentiate Changshan from non-Changshan camellia oils, even from the adjacent counties. Moreover, compared with traditional indicators of mineral elements, the model built by fatty acid profiles possessed higher sensitivity and specificity. It also offered a reference strategy for the geographical origin identification of other high-value oils or foods.

摘要

地理标志(GI)农产品具有特定的地理来源和高品质,这对于重要的保护商标来说需要一种有效的地理来源可追溯方法。在本研究中,通过脂肪酸谱和包括数据驱动的类类比软独立建模(DD-SIMCA)和一类偏最小二乘法(OCPLS)在内的一类分类方法,开发了常山山茶油的认证模型,并与传统的二类分类模型进行了比较。结果表明,对于来自目标地理来源之外的样本,三种二类分类模型的预测误差分别为63.8%、12.1%和65.2%。相比之下,一类分类模型可以完全区分常山山茶油和非常山山茶油,甚至能区分来自相邻县的山茶油。此外,与传统的矿物元素指标相比,由脂肪酸谱构建的模型具有更高的灵敏度和特异性。它还为其他高价值油脂或食品的地理来源鉴定提供了参考策略。

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