Mahalingam Shanmugam, Neelan Yalini Devi, Bakthavatchalam Senthil, Al-Humaid Latifah A, Al-Dahmash Nora Dahmash, Santhanam Harikrishnan, Yang Tae-Youl, Hossain Nazmul, Park Sung Heum, Kim Junghwan
Department of Materials System Engineering, Pukyong National University, Busan 48513, Republic of Korea.
Department of Materials Science and Engineering, Chungnam National University, Daejeon 34134, Republic of Korea.
ACS Omega. 2023 Aug 28;8(36):32817-32827. doi: 10.1021/acsomega.3c03883. eCollection 2023 Sep 12.
In recent decades, antibiotics have been found in aquatic environments, raising severe concerns. In this study, a unique reduced graphene oxide-zinc sulfide-copper sulfide (rGO-ZnS-CuS) nanocomposite (NC) prepared by using a straightforward surfactant-free microwave method was used for antibiotic degradation via photocatalysis. The structural and morphological characteristics of the produced catalysts were characterized using various techniques, confirming the successful development of nanocomposite structures of better quality than that of the pure samples. The photocatalytic degradation of antibiotics containing ofloxacin was also investigated. The results suggest that the rGO-ZCS NC outperformed the other composites in terms of photocatalytic activity toward ofloxacin degradation. Superoxide and hydroxyl radicals were the main active species during the degradation process. According to our results, the catalytic activity of rGO-ZCS NC is much better than that of the other composites.
近几十年来,在水生环境中发现了抗生素,这引起了人们的严重关注。在本研究中,通过一种简单的无表面活性剂微波法制备的独特的还原氧化石墨烯-硫化锌-硫化铜(rGO-ZnS-CuS)纳米复合材料(NC)被用于通过光催化降解抗生素。使用各种技术对所制备催化剂的结构和形态特征进行了表征,证实成功开发出了质量优于纯样品的纳米复合结构。还研究了含氧氟沙星抗生素的光催化降解。结果表明,rGO-ZCS NC在对氧氟沙星降解的光催化活性方面优于其他复合材料。超氧自由基和羟基自由基是降解过程中的主要活性物种。根据我们的结果,rGO-ZCS NC的催化活性比其他复合材料要好得多。