Popescu Aurelian, Savastru Dan, Stafe Mihai, Puscas Nicolae
National Institute of R & D for Optoelectronics INOE 2000, 409 Atomistilor Str., 077125 Magurele, Romania.
Department of Physics, University Politehnica of Bucharest, 313 Splaiul Independentei, 060042 Bucharest, Romania.
Materials (Basel). 2023 Sep 7;16(18):6110. doi: 10.3390/ma16186110.
The paper is a review of surface plasmon resonance (SPR) structures containing amorphous chalcogenide (ChG) films as plasmonic waveguides. The calculation method and specific characteristics obtained for four-layer SPR structures containing films made of amorphous AsS and AsSe are presented. The paper is mainly based on our previously obtained and published scattered results, to which a generalized point of view was applied. In our analysis, we demonstrate that, through proper choice of the SPR structure layer parameters, we can control the resonance angle, the sharpness of the SPR resonance curve, the penetration depth, and the sensitivity to changes in the refractive index of the analyte. These results are obtained by operating with the thickness of the ChG film and the parameters of the coupling prism. Aspects regarding the realization of the coupling prism are discussed. Two distinct cases are analyzed: first, when the prism is made of material with a refractive index higher than that of the waveguide material; second, when the prism is made of material with a lower refractive index. We demonstrated experimentally that the change in reflectance self-induced by the modification in AsS refractive index exhibits a hysteresis loop. We present specific results regarding the identification of alcohols, hydrocarbons, and the marker of bacteria.
本文是一篇关于包含非晶硫属化物(ChG)薄膜作为等离子体波导的表面等离子体共振(SPR)结构的综述。介绍了包含非晶AsS和AsSe薄膜的四层SPR结构的计算方法和特定特性。本文主要基于我们之前获得并发表的分散结果,并应用了广义的观点。在我们的分析中,我们证明,通过适当选择SPR结构层参数,可以控制共振角、SPR共振曲线的锐度、穿透深度以及对分析物折射率变化的灵敏度。这些结果是通过调整ChG薄膜的厚度和耦合棱镜的参数获得的。讨论了关于耦合棱镜实现的方面。分析了两种不同的情况:第一,当棱镜由折射率高于波导材料的材料制成时;第二,当棱镜由折射率较低的材料制成时。我们通过实验证明,AsS折射率变化自诱导的反射率变化呈现出滞后回线。我们给出了关于醇类、烃类和细菌标志物识别的具体结果。