Gao Xinlei, Cheng Yuwei, Shi Miaomiao, Chen Hao, Wu Li, Wang Tingting
School of Materials Science and Engineering, Hubei University, Wuhan 430062, China.
School of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China.
Polymers (Basel). 2023 Sep 7;15(18):3693. doi: 10.3390/polym15183693.
Polyimide (PI) is a high-performance engineering plastic used as a bearing material. A superlubricity system using SiN/PI as the friction pair and nematic liquid crystals (LCs) as the lubricant was designed. The superlubricity performance was studied by simulating the start-stop condition of the machine, and it was found that the superlubricity system had good reproducibility and stability. In the superlubricity system, friction aligned with the PI molecules, and this alignment was less relevant compared to which substance was rubbing on the PI. Oriented PI molecules induced LC molecule alignment when the pretilt angle was very small, and the LC molecules were almost parallel to the PI molecules due to the one-dimensional ordered arrangement of LC molecules and low viscosity, which is conducive to the occurrence of the superlubricity phenomenon.
聚酰亚胺(PI)是一种用作轴承材料的高性能工程塑料。设计了一种以SiN/PI为摩擦副、向列型液晶(LCs)为润滑剂的超润滑系统。通过模拟机器的启停条件研究了超润滑性能,发现该超润滑系统具有良好的重现性和稳定性。在超润滑系统中,摩擦力与PI分子对齐,与哪种物质在PI上摩擦相比,这种对齐的相关性较小。当预倾角非常小时,取向的PI分子会诱导LC分子排列,并且由于LC分子的一维有序排列和低粘度,LC分子几乎与PI分子平行,这有利于超润滑现象的发生。