Avila Jocasta, Corsini Chiara, Correa Cintia M, Rosenthal Martin, Padua Agilio, Costa Gomes Margarida
Laboratoire de Chimie de l'ENS Lyon, CNRS and Université de Lyon, 46 allée d'Italie, 69364 Lyon, France.
Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Box 2404, 3001 Leuven, Belgium.
ACS Nano. 2023 Oct 24;17(20):19508-19513. doi: 10.1021/acsnano.3c06343. Epub 2023 Oct 9.
This Perspective points toward pathways to prepare porous ionic liquids using easily accessible materials, aiming for reduced environmental impact. We demonstrate that suspensions of porous solids are stable in eutectic mixtures, underscoring their potential for the preparation of porous ionic liquids. Porous ionic liquids retain the wide electrochemical window observed in their precursor pure ionic liquids, rendering them well-suited for green electrochemical reactions, particularly those involving gases whose solubility is enhanced in the porous suspensions. Moreover, their capacity as gas-rich media points to sustainable biomedical and pharmaceutical applications, provided nontoxic, biocompatible ionic liquids and porous solids are utilized.
这篇观点文章指出了使用易于获取的材料制备多孔离子液体的途径，旨在减少对环境的影响。我们证明了多孔固体悬浮液在低共熔混合物中是稳定的，这突出了它们在制备多孔离子液体方面的潜力。多孔离子液体保留了其前体纯离子液体中观察到的宽电化学窗口，使其非常适合绿色电化学反应，特别是那些涉及在多孔悬浮液中溶解度增加的气体的反应。此外，它们作为富含气体介质的能力表明了其在可持续生物医学和制药应用中的潜力，前提是使用无毒、生物相容的离子液体和多孔固体。
