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多孔低共熔溶剂——未实现的梦想还是科学创新的下一个突破?

Porous Deep Eutectic Solvents-Unfulfilled Dream or the Next Breakthrough in Scientific Innovation?

作者信息

Wysokowski Marcin, Makoś-Chełstowska Patrycja, Brzęczek-Szafran Alina, Sikora Aleksandra, Gorczyński Adam, Jesionowski Teofil

机构信息

Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, Berdychowo 4, Poznan, 60965, Poland.

Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, Gdańsk, 80-233, Poland.

出版信息

Adv Sci (Weinh). 2025 Feb;12(5):e2412622. doi: 10.1002/advs.202412622. Epub 2024 Dec 24.

DOI:10.1002/advs.202412622
PMID:39716955
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11791985/
Abstract

Porous deep eutectic solvents (PDES) are capturing the imagination of scientists, promising a revolutionary leap in material science. These innovative materials, blending the versatility of deep eutectic solvents (DES) with the intricate architectures of porous structures, offer an exciting array of applications-from green chemistry and catalysis to energy storage and environmental remediation. However, the journey from laboratory curiosity to industrial application is fraught with challenges. This perspective article analyzes the realm of PDES, scrutinizing the cutting-edge advancements and the challenges that lie ahead. By exploring their synthesis, unique properties, and diverse application potential, the critical question is asked: are PDES an unfulfilled dream or the next big breakthrough in scientific innovation? A comprehensive analysis reveals a "landscape" ripe with opportunity, suggesting that with targeted research and development, PDES can indeed become a cornerstone technology, driving progress across multiple scientific domains.

摘要

多孔深共熔溶剂(PDES)正激发着科学家们的想象力,有望在材料科学领域实现革命性飞跃。这些创新材料将深共熔溶剂(DES)的多功能性与多孔结构的复杂架构相结合,提供了一系列令人兴奋的应用——从绿色化学和催化到能量存储和环境修复。然而,从实验室的新奇事物走向工业应用的道路充满挑战。这篇观点文章分析了PDES领域,审视了前沿进展以及未来面临的挑战。通过探索它们的合成、独特性质和多样的应用潜力,提出了一个关键问题:PDES是一个未实现的梦想,还是科学创新的下一个重大突破?全面分析揭示了一个充满机遇的“前景”,表明通过有针对性的研发,PDES确实可以成为一项基石技术,推动多个科学领域的进步。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01e2/11791985/677424b5b13e/ADVS-12-2412622-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01e2/11791985/a0b911494f8f/ADVS-12-2412622-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01e2/11791985/677424b5b13e/ADVS-12-2412622-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01e2/11791985/a0b911494f8f/ADVS-12-2412622-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/01e2/11791985/677424b5b13e/ADVS-12-2412622-g005.jpg

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本文引用的文献

1
How Do Deep Eutectic Solvents Form Porous Liquids? The Example of Methyltriphenylphosphonium Bromide: Glycerol and ZIF-8.深共熔溶剂如何形成多孔液体?以甲基三苯基溴化鏻:甘油和ZIF-8为例。
J Phys Chem B. 2024 Mar 14;128(10):2481-2489. doi: 10.1021/acs.jpcb.3c08490. Epub 2024 Mar 4.
2
Polymer-Coated Covalent Organic Frameworks as Porous Liquids for Gas Storage.聚合物包覆的共价有机框架作为用于气体存储的多孔液体
Chem Mater. 2024 Jan 19;36(3):1579-1590. doi: 10.1021/acs.chemmater.3c02828. eCollection 2024 Feb 13.
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Incorporating Photoresponses into Porous Liquids.
将光响应纳入多孔液体中。
Chemistry. 2024 Mar 15;30(16):e202303593. doi: 10.1002/chem.202303593. Epub 2024 Jan 11.
4
Porous Ionic Liquids Go Green.多孔离子液体走向绿色环保。
ACS Nano. 2023 Oct 24;17(20):19508-19513. doi: 10.1021/acsnano.3c06343. Epub 2023 Oct 9.
5
A porous metal-organic cage liquid for sustainable CO conversion reactions.一种用于可持续 CO 转化反应的多孔金属有机笼液体。
Nat Commun. 2023 Jun 7;14(1):3317. doi: 10.1038/s41467-023-39089-x.
6
VOCs absorption from gas streams using deep eutectic solvents - A review.使用深共晶溶剂从气流中吸收 VOCs-综述。
J Hazard Mater. 2023 Apr 15;448:130957. doi: 10.1016/j.jhazmat.2023.130957. Epub 2023 Feb 9.
7
Porous Liquids Responsive to Light.对光有响应的多孔液体。
Angew Chem Int Ed Engl. 2022 Dec 12;61(50):e202212326. doi: 10.1002/anie.202212326. Epub 2022 Nov 15.
8
Porous liquids - the future is looking emptier.多孔液体——未来看起来更加空洞。
Chem Sci. 2022 Apr 25;13(18):5042-5054. doi: 10.1039/d2sc00087c. eCollection 2022 May 11.
9
The changing state of porous materials.多孔材料的变化状态。
Nat Mater. 2021 Sep;20(9):1179-1187. doi: 10.1038/s41563-021-00957-w. Epub 2021 Apr 15.
10
Engineering Permanent Porosity into Liquids.在液体中制造永久性孔隙率。
Adv Mater. 2021 May;33(18):e2005745. doi: 10.1002/adma.202005745. Epub 2021 Mar 26.