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锰基金属间化合物MnAl和Mn(= V、Cr、Fe、Co、Ni;= Al、Ge、Sn、Si、Pt)的磁态和电子性质

Magnetic States and Electronic Properties of Manganese-Based Intermetallic Compounds MnAl and Mn ( = V, Cr, Fe, Co, Ni; = Al, Ge, Sn, Si, Pt).

作者信息

Marchenkov Vyacheslav V, Irkhin Valentin Yu

机构信息

Mikheev Institute of Metal Physics, Ural Branch of Russian Academy of Sciences, 620108 Ekaterinburg, Russia.

出版信息

Materials (Basel). 2023 Sep 22;16(19):6351. doi: 10.3390/ma16196351.

Abstract

We present a brief review of experimental and theoretical papers on studies of electron transport and magnetic properties in manganese-based compounds Mn and Mn ( = V, Cr, Fe, Co, Ni, etc.; = Al, Ge, Sn, Si, Pt, etc.). It has been shown that in the electronic subsystem of Mn compounds, the states of a half-metallic ferromagnet and a spin gapless semiconductor can arise with the realization of various magnetic states, such as a ferromagnet, a compensated ferrimagnet, and a frustrated antiferromagnet. Binary compounds of Mn have the properties of a half-metallic ferromagnet and a topological semimetal with a large anomalous Hall effect, spin Hall effect, spin Nernst effect, and thermal Hall effect. Their magnetic states are also very diverse: from a ferrimagnet and an antiferromagnet to a compensated ferrimagnet and a frustrated antiferromagnet, as well as an antiferromagnet with a kagome-type lattice. It has been demonstrated that the electronic and magnetic properties of such materials are very sensitive to external influences (temperature, magnetic field, external pressure), as well as the processing method (cast, rapidly quenched, nanostructured, etc.). Knowledge of the regularities in the behavior of the electronic and magnetic characteristics of MnAl and Mn compounds can be used for applications in micro- and nanoelectronics and spintronics.

摘要

我们简要综述了关于锰基化合物Mn 和Mn (其中 = V、Cr、Fe、Co、Ni等; = Al、Ge、Sn、Si、Pt等)中电子输运和磁性研究的实验及理论论文。研究表明,在Mn化合物的电子子系统中,随着铁磁体、补偿亚铁磁体和受挫反铁磁体等各种磁态的实现,可能会出现半金属铁磁体和自旋无隙半导体的状态。Mn的二元化合物具有半金属铁磁体和拓扑半金属的性质,伴有大的反常霍尔效应、自旋霍尔效应、自旋能斯特效应和热霍尔效应。它们的磁态也非常多样:从亚铁磁体和反铁磁体到补偿亚铁磁体和受挫反铁磁体,以及具有 kagome 型晶格的反铁磁体。已经证明,这类材料的电子和磁性对外部影响(温度、磁场、外部压力)以及加工方法(铸造、快速淬火、纳米结构化等)非常敏感。了解MnAl和Mn化合物电子和磁性特性的行为规律可用于微电子和自旋电子学领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aba4/10573737/f85e8d7e65a8/materials-16-06351-g001.jpg

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