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研究三种聚合物在不同氯浓度和暴露时间下的降解情况。

Studying the Degradation of Three Polymers under Different Chlorine Concentrations and Exposure Times.

作者信息

Barbosa Marta L S, Costa Rúben D F S, Silva Francisco J G, Sousa Susana R, Pinto Arnaldo G, Ferreira Bruno O

机构信息

ISEP, Polytechnic of Porto, 4249-015 Porto, Portugal.

INEGI-Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal.

出版信息

Polymers (Basel). 2023 Sep 29;15(19):3931. doi: 10.3390/polym15193931.

Abstract

Due to chlorine's ability to kill bacteria and fungi through a chemical reaction, chlorine solutions are commonly used to clean and disinfect numerous public facilities, although these actions are also dependent to the equipment present in those facilities. Accordingly, the interest in studying its effect when in contact with different materials is obvious. This study was carried out through accelerated degradation tests and various analysis methods (optical microscope, scanning electron microscope, and tensile tests). The objective was to observe the wear presented by three polymeric materials, polyvinyl chloride (PVC), high-density polyethylene (HDPE), and polypropylene (PP), when exposed to chlorine's action in swimming pools and drinking water treatment plants. The resulting effect depends on the chlorine content and the type of contact between the chemical agent and the material. The aim was to select the material less likely to be affected by chlorine through tests and analyses, allowing a longer component life. The use of certain more resistant polymeric materials can drastically reduce maintenance, reducing fundamental factors such as costs, the downtime of municipal facilities, and also the risk to public health. It was concluded that PVC has the most stable behaviour overall when in contact with chlorine solutions.

摘要

由于氯能够通过化学反应杀死细菌和真菌,氯溶液通常用于清洁和消毒众多公共设施,不过这些行动也取决于这些设施中所配备的设备。因此,研究氯与不同材料接触时的效果的兴趣是显而易见的。本研究通过加速降解试验和各种分析方法(光学显微镜、扫描电子显微镜和拉伸试验)进行。目的是观察三种聚合材料,即聚氯乙烯(PVC)、高密度聚乙烯(HDPE)和聚丙烯(PP),在游泳池和饮用水处理厂中暴露于氯的作用下时所呈现的磨损情况。产生的效果取决于氯含量以及化学试剂与材料之间的接触类型。目的是通过测试和分析选择受氯影响可能性最小的材料,从而延长部件使用寿命。使用某些更具耐受性的聚合材料可以大幅减少维护工作,降低诸如成本、市政设施停机时间以及对公众健康的风险等基本因素。得出的结论是,PVC在与氯溶液接触时总体表现最为稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f410/10574910/dc67b3ff58af/polymers-15-03931-g0A1.jpg

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