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Ti-10Nb 合金的粉末冶金加工路线开发用于牙科应用。

Development of Ti-10Nb alloy by powder metallurgy processing route for dental application.

机构信息

Department of Mechanical Engineering, Indian Institute of Technology, Banaras Hindu University, Varanasi, India.

出版信息

J Biomed Mater Res B Appl Biomater. 2024 Jan;112(1):e35338. doi: 10.1002/jbm.b.35338. Epub 2023 Oct 17.

DOI:10.1002/jbm.b.35338
PMID:37846459
Abstract

Titanium and its alloys are used to make dental implants because of its low density, high strength, and corrosion resistance. This paper describes the development of a potential biomaterial Ti-10Nb by powder metallurgy utilizing four different compaction pressures and analyses its microstructural, physical, mechanical, electrochemical, biological, and tribological behavior under various situations. The alloys were fabricated using four different compaction pressures, that is, 600, 650, 700, and 750 MPa, and sintered in a vacuum atmosphere at 1000°C for 1.5 h. The density of the samples was measured using Archimedes principle. X-ray diffraction and scanning electron microscopy equipped with energy dispersive spectroscopy were used to investigate the phase composition and microstructure, and a profilometer was used to examine the surface roughness of various samples. Vickers hardness tester was used to evaluate hardness, and a universal testing machine was used for compression testing. Corrosion and wear behavior were examined using a potentiostat and a Bio-Tribometer, respectively. This Ti-10Nb alloys consist of α + β phase, and have 16% highest porosity in sample compacted at 600 MPa. The samples compacted at 750 MPa achieved highest hardness, yield strength, compressive strength, and elastic modulus of 450 ± 29.72 HV, 718.22 ± 16.37 MPa, 1543.59 ± 24.37 MPa, and 41.27 ± 3.29 GPa, respectively. In addition, it also possesses highest corrosion and wear resistance with lowest i of 0.3954 ± 0.008 μA/cm and wear volume of (31.25 ± 0.206) × 10  mm . These results indicate that the developed alloys have a variety of desirable properties, including high hardness, adequate compressive strength, good corrosion and wear resistance, apatite-forming capability, and a low elastic modulus, which is advantageous for avoiding stress shielding. Therefore, it may be recommended to use it as a dental implant material.

摘要

钛及其合金因其低密度、高强度和耐腐蚀性而被用于制造牙科植入物。本文描述了一种通过粉末冶金技术开发的潜在生物材料 Ti-10Nb,该技术利用四种不同的压实压力,并分析了其在各种情况下的微观结构、物理、机械、电化学、生物和摩擦学性能。合金是通过四种不同的压实压力(600、650、700 和 750 MPa)制造的,并在 1000°C 的真空气氛中烧结 1.5 小时。使用阿基米德原理测量样品的密度。使用 X 射线衍射和扫描电子显微镜(配备能量色散光谱仪)研究相组成和微观结构,使用轮廓仪检查各种样品的表面粗糙度。使用维氏硬度计评估硬度,使用万能试验机进行压缩试验。使用电位计和生物摩擦计分别检查腐蚀和磨损行为。这种 Ti-10Nb 合金由 α+β 相组成,在 600 MPa 下压实的样品中具有 16%的最高孔隙率。在 750 MPa 下压实的样品获得了最高的硬度、屈服强度、抗压强度和弹性模量,分别为 450±29.72 HV、718.22±16.37 MPa、1543.59±24.37 MPa 和 41.27±3.29 GPa。此外,它还具有最高的耐腐蚀性和耐磨性,具有最低的 i 值为 0.3954±0.008 μA/cm 和磨损体积为 (31.25±0.206)×10 -3 mm 。这些结果表明,所开发的合金具有多种理想的性能,包括高硬度、足够的抗压强度、良好的耐腐蚀性和耐磨性、磷灰石形成能力以及低弹性模量,这有利于避免应力屏蔽。因此,建议将其用作牙科植入物材料。

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